![陳小明[無機化學家、中國科學院院士]](/img/d/6bc/nBnauM3X2gDN2MjN2EDO2kTO0UTMyITNykTO0EDMwAjMwUzLxgzL0EzLt92YucmbvRWdo5Cd0FmLxE2LvoDc0RHa.jpg "陳小明[無機化學家、中國科學院院士]")
人物經歷
陳小明1961年10月5日，生於廣東省揭陽市。
1983年，獲中山大學理學學士學位。
1986年，獲中山大學理學碩士學位。
1992年，獲香港中文大學哲學博士學位。
1986年至1989年，在中山醫科大學生物化學教研室工作，歷任助教、講師。
1992年7月，在中山大學化學與化學工程學院工作，副教授（1993年12月晉升）、教授（1995年1月晉升）。
2000年至2004年，長江學者特聘教授。
2006年，擔任生物無機與合成化學教育部重點實驗室主任 。曾擔任中山大學化學與化學工程學院院長 。
學術兼職
作為第一完成人獲國家自然科學獎二等獎一項和廣東省自然科學獎一等獎兩項，並先後獲得香港求是科技基金會“傑出青年學者獎”、第五屆“中國青年科技獎”，以及教育部“全國優秀教師”等個人獎勵。
國務院學位委員會第六屆學科評議組成員；中國晶體學會副理事長，中國化學會理事，中國稀土學會理事；《無機化學學報》副主編，《結構化學》和《中國稀土學報》雜誌編委，Chemcal Communications (RSC) ， CrystEngComm (RSC)，Crystal Growth & Design (ACS)，European Journal of Inorganic Chemistry (Wiley)，Polyhedron (Elsevier)等國際學術刊物的顧委或編委； 十多種國際性學術雜誌(包括《美國化學會會志》、美國《無機化學》）和10種國內學術雜誌（包括《中國科學》、《 化學學報》、《中國化學》、《科學通報》、《高校化學學報》等）審稿人。
科研成果
他主要從事功能金屬配合物和聚合金屬配合物超分子體系的分子設計、合成和結構與性能研究。目前已取得的主要研究成果有三個方面：
(1) 1992年起，開展“金屬酶活性中心構的小分子模擬”的研究，取得具有特色的進展，合成了多種金屬酶活性中心結構的新型模型化 合物並進行深入的結構與催化性質研究。
(2) 1994年起，開展了“具有光電子性能的簇合物與聚合物研究”，創立合成含銅與其它金屬的異多核配合物的獨特方法，設計和組裝新 型異多核金屬配合物，在複雜異多核金屬配合物的分子設計與合成方面取得新的突破，成功建立起系列銅－稀土18核簇合物及其它銅－稀土異 多核配合物的新穎製備方法，開展複雜金屬配合物體系的磁性及光電性質研究，為異金屬功能配合物在分子光電器件中的套用研究提供了新的 基礎。
（3）成功利用橋連配體與金屬離子作為模組組裝了大量的、具有不同框架結構的聚合金屬配合物，並通過超分子作用等調控聚合物的框架 結構，獲得系列具有新穎結構和發光功能等功能的新型有機—金屬聚合物，為此類新型無機—有機雜化材料的研製提出新的研究思路和方向。
1993年以來，主持包括國家傑出青年科學基金和國家基金重點項目等10多項國家和省部級科學基金課題。迄今在國內外學術雜誌上發表學 術論文230多篇，其中在包括國際第一流的化學雜誌《美國化學會會志》、德國《套用化學》、《歐洲化學》等知名學術刊物發表200多篇。部 分論文已被同行在國際性學術雜誌上引證1160多次。根據國家科委情報中心的統計，1996年陳小明在國際上發表（《SCI》收錄）的論文居全國個人排行榜第五位，1997年國際論文被引用篇數全國個人排位第三名。1999年國際論文被引用篇數全國個人排位第三名。曾應邀在13次國際性 和17次全國性學術會議上作邀請報告。在教學方面，他曾講授《結構化學》、《波譜化學》、《X射線單晶結構分析》和《金屬配合物的現代研究方法》、《現代無機化學》、《 配位化學》等本科生、研究生課程。指導博士後、博士生、碩士生等的科研工作，其中7名博士生和6名碩士生已畢業並獲得相應學位。他指導的一名博士生的學位論文被評為“全國優秀博士論文”（2001年）。
獲得榮譽
由於他在科研和教學等方面取得的成績，1996年獲國家傑出青年科學基金的資助。1997年獲第五屆“中國青年科技獎”，首屆“廣東省優秀青年科學家獎”。1998年，獲廣東省自然科學獎一等獎（第一完成人）、廣東省“十大傑出青年”稱號。入選國家“百千萬”人才工程97年度第一、二層次人選。1999年獲得求是科學基金會“傑出青年學者獎”。2000年獲得中國高等學校科學技術獎二等獎（第三完成人）。2002年獲得中國高等學校科學技術獎二等獎（第一完成人）。 2007年獲國家自然科學獎二等獎。
科研論文
近年作為通訊作者發表的部分論文目錄：
2009
1. Optimized acetylene/carbon dioxide sorption in a dynamic porous crystal Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2008, ja-2008-089872.
2. Two metal-carboxylate frameworks featuring uncommon 2D + 3D and 3-fold interpenetration: (3,5) connected isomeric hms and gra nets Hou, L.; Zhang, J.-P.; Chen, X.-M., Cryst. Growth Des. 2009, cg-2008-01308u.
3. Isomeric zinc(II) triazolate frameworks with 3-connected networks: syntheses, structures, and sorption properties Zhu, A.-X.; Lin, J.-B.; Zhang, J.-P.; Chen, X.-M., Inorg. Chem. 2009, ic-2008-02446m.
4. A spin-frustrated complex, [FeIIFeIII(trans-1, 4-cyclohexanedicarboxylate)1.5]∞: Interplay between single-chain magnet behavior and magnetic ordering Zheng, Y.-Z.; Xue, W.; Zhang, W.-X.; Tong, M. L.; Chen, X.-M.; Grandjean F.; Long G. J.; Ng, S. W.; Panissod P.; Drillon M., Inorg. Chem. 2009, 48, 2028–2042.
5. Syntheses, structures and magnetic properties of a family of metal carboxylate polymers via in-situ metal/ligand reactions of benzene-1,2,3-tricarboxylic acid Zheng, Y.-Z.; Zhang, Y.-B.; Tong, M.-L.; Xue W.; Chen, X.-M.; Dalton Trans 2009, 1396-1406.
6. Syntheses, structures and sorption properties of two framework-isomeric porous copper coordination polymers Xue D.-X.; Lin, J.-B.; Zhang, J.-P.; Chen, X.-M., CrystEngComm 2009, 11, 183-188.
2008
7. Probing single-chain magnets in a family of linear chain compounds constructed by magnetically anisotropic metal-ions and cyclohexane-1,2-dicarboxylate analogues Zheng, Y.-Z.; Xue, W.; Tong, M.-L.; Chen, X.-M.; Zheng, S.-L., Inorg. Chem. 2008, 47, 11202–11211.
8. Microwave-assisted solvothermal synthesis of a dynamic nanoporous metal-carboxylate framework Wang, X.-F.; Zhang, Y.-B.; Huang, H.; Zhang, J.-P.; Chen, X.-M., Cryst. Growth Des. 2008, 8, 4559-4563.
9. Pillaring Zn-triazolate layers with flexible aliphatic dicarboxylates into three-dimensional metal-organic frameworks Lin, Y.-Y.; Zhang, Y.-B.; Zhang, J.-P.; Chen, X.-M., Cryst. Growth Des. 2008, 8, 3673–3679.
10. (Hot Paper) Assembly of 3D geometrically frustrated magnets with tranistion metal ion and 1,2,3-triazole-4,5-dicarboxylate as triangular nodes Zhang, W.-X.; Xue, W.; Lin, J.-B.; Zheng, Y.-Z.; Chen, X.-M., CrystEngComm 2008, 10, 1770-1776.
11. Two highly-connected, chiral, porous coordination polymers featuring novel heptanuclear metal carboxylate clusters Hou, L.; Zhang, J.-P.; Chen, X.-M.; Ng, S.W., Chem. Commun. 2008, 4019–4021.
12. Weak ferromagnetism and dynamic magnetic behaviors of two 2D compounds with hydroxy/carboxylate-bridged Co(II) chains Cheng, X.-N., Xue, W., Zhang, W.-X., Chen, X.-M., Chem. Mater. 2008, 20, 5345–5350.
13. Pentanuclear and heptanuclear metal helicates by self-assembly of d metal ions and a rigid aromatic bis-bidentate chelator Zhu, A.-X., Zhang, J.-P., Lin, Y.-Y., Chen, X.-M., Inorg. Chem. 2008, 47, 7389-7395..
14. Two microporous metal-organic frameworks with different topologies constructed from linear trinuclear M3(COO)n secondary building units Wang, X.-F., Zhang, Y.-B., Cheng, X.-N., Chen, X.-M., CrystEngComm 2008, 10, 753–758.
15. A two-dimensional iron(II) carboxylate linear chain polymer that exhibits a metamagnetic spin-canted antiferromagnetic to single-chain magnetic transition Zheng, Y.-Z., Xue, W., Tong, M.-L., Zhang, W.-X., Chen, X.-M., Grandjean F.; Long G. J., Inorg. Chem. 2008, 47, 4077-4087.
16. Exceptional framework flexibility and sorption behavior of a multifunctional porous cuprous triazolate framework Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2008, 130, 6010–6017.
17. Néel temperature enhanced by increasing the in-plane magnetic correlation in layered inorganic-organic hybrid materials Zheng, Y.-Z.; Xue W.; Zheng, S.-L.; Tong, M.-L. ; Chen, X.-M., Adv. Mater. 2008, 20, 1534–1538.
18. Single-crystal-to-single-crystal transformation involving release of bridging water molecules and transform of chain helicity in a chiral three-dimensional metal-organic framework Xue, D.-X.; Zhang, W.-X.; Chen, X.-M.; Wang, H.-Z., Chem. Commun. 2008, 1551-1553.
19. Porous metal-organic framework based on μ4-oxo tetrazinc clusters: sorption and guest-dependent luminescent properties Hou, L.; Lin, Y.-Y.; Chen, X.-M., Inorg. Chem. 2008, 47, 1346-1351.
2007
20. Single-crystal-to-single-crystal transformation from ferromagnetic discrete molecules to a spin canting antiferromagnetic layer Cheng, X.-N.; Zhang, W.-X.; Chen, X.-M., J. Am. Chem. Soc. 2007, 129, 15738-15739.
21. Rational construction and hydrogen storage behavior of a dynamic microporous metal-organic framework with BCT zeolite topology, Hu, S.; Zhang, J.-P.; Tong, M.-L.; Chen, X.-M.; Kitagawa, S. Cryst. Growth Des. 2007, 7, 2286-2289.
22. A “star” antiferromagnet: A polymeric iron(III) acetate exhibiting the coexistence of spin-frustration and long-range magnetic order Zheng, Y.-Z.; Tong, M.-L.; Xue, W.; Zhang, W.-X.; Chen, X.-M.; Grandjean, F.; Long, G. J., Angew. Chem. Int. Ed. 2007, 46, 6076-6080. (Highlighted in Nature China)
23. From pseudo to true C3-symmetry: Magnetic anisotropy enhanced by site-specific ligand substitution in two Mn15-carboxylate clusters Zheng, Y.-Z.; Zhang, W.-X.; Xue, W.; Tong, M.-L.; Chen, X.-M., Inorg. Chem. 2007, 46, 6437-6443.
24. A tetracarboxylate–bridged dicopper(II) paddle-wheel-based 2-D porous coordination polymer with gas sorption properties Xue, D.-X; Lin, Y.-Y.; Cheng, X.-N.; Chen, X.-M., Cryst. Growth Des. 2007, 7, 1332-1336.
25. Unprecedented (3,9)-connected (4.6)3(4.6.8) net constructed by trinclear mixed-valence cobalt clusters Zhang, X.-M.; Zheng, Y.-Z.; Li, C.-R.; Zhang, W.-X.; Chen, X.-M., Cryst. Growth Des. 2007, 7, 980–983.
26. A dynamic porous magnet exhibiting reversible guest-induced magnetic behavior modulation Cheng, X.-N.; Zhang, W.-X.; Lin, Y.-Y.; Zheng, Y.-Z.; Chen, X.-M., Adv. Mater. 2007, 19, 1494–1498.
27. Solvothermal in-situ metal/ligand reactions: A new bridge between coordination chemistry and organic synthetic chemistry Chen, X.-M.; Tong, M.-L., Acc. Chem. Res. 2007, 40, 162-170.
28. In situ solvothermal generation of 1,2,4-triazolates and related compounds from organonitriles and hydrazine hydrate: A mechanism study Cheng, L.; Zhang, W.-X.; Ye, B.-H.; Lin, J.-B.; Chen, X.-M., Inorg. Chem. 2007, 46, 1135-1143.
2006
29. Encapsulation of water cluster, meso-helical chain and tapes in metal-organic frameworks based on double-stranded Cd(II) helicates and carboxylates Cheng, L.; Lin, J.-B.; Gong, J.-Z.; Sun, A.-P.; Ye, B.-H.; Chen, X.-M., Cryst. GrowthDes. 2006, 6, 2739-2746.
30. A robust microporous 3D cobalt(II) coordination polymer with new magnetically frustrated 2D lattices: single-crystal transformation and guest modulation of cooperative magnetic properties Zeng, M.-H.; Feng, X.-L.; Zhang, W.-X.; Chen, X.-M., Dalton Trans. 2006, 5294-5303.
31. Chiral magnetic metal-organic frameworks of dimetal sub-units: Magnetism tuning by mixed-metal compositions of the solid solutions Zeng, M.-H.; Wang, B.; Wang, X.-Y.; Zhang, W.-X.; Chen, X.-M., Gao, S. Inorg. Chem. 2006, 45, 7069-7076.
32. Assembling “magnetic nanowires” into network: A layered Co(II)-carboxylate coordination polymer exhibiting single-chain-magnet behavior Zheng, Y.-Z.; Tong, M.-L.; Zhang, W.-X.; Chen, X.-M., Angew. Chem. Int. Ed. 2006, 45, 6310-6314.
33. The slow magnetic relaxation observed in a mixed carboxylate/hydroxide-bridged compound [Co2Na(4-cpa)2(m3-OH)(H2O)]¥ featuring spin-frustrated magnetic D-chains Cheng, X.-N.; Zhang, W.-X.; Zheng, Y.-Z.; Chen, X.-M., Chem. Commun. 2006, 3603-3605.
34. Syntheses, structures and photoluminescence of three coordination polymers of cadmium dicarboxylates Zhang, L.-Y.; Zhang, J.-P.; Lin, Y.-Y.; Chen, X.-M., Cryst. Growth Des. 2006, 6, 1684-1689.
35. Solvent-induced supramolecular isomerism in silver(I) 2-methylimidazolate Huang, X.-C.; Li, D.; Chen, X.-M., CrystEngComm 2006, 8, 351-355.
36. One-dimensional supramolecular isomerism of copper(I) and silver(I) imidazolates based on the ligand orientations Huang, X.-C.; Zhang, J.-P.; Chen, X.-M., Cryst. Growth Des. 2006, 6, 1194-1198.
37. (Feature Article) Crystal engineering of binary metal imidazolate and triazolate frameworks Zhang, J.-P.; Chen, X.-M., Chem. Commun. 2006, 1689-1699.
38. Ligand-directed strategy for zeolite-type metal-organic frameworks: Zinc(II) imidazolates with unusual zeolitic topologies Huang, X.-C.; Lin, Y.-Y.; Zhang, J.-P.; Chen, X.-M., Angew. Chem. Int. Ed. 2006, 45, 1557-1559.
39. From one- to three-dimensional architectures: Supramolecular isomerism of copper(I) 3,5-di(4-pyridyl)-1,2,4-triazolate involving in situ ligand synthesis Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M., Cryst. Growth Des. 2006, 6, 519–523.
40. Coexistence of spin frustration and long-range magnetic ordering in a triangular Co3(m3-OH)-based two-dimensional compound Zheng, Y.-Z.; Tong, M.-L.; Zhang, W.-X.; Chen, X.-M., Chem. Commun. 2006, 165–167.
2005
41. Synthesis, structures, magnetic properties of heteronuclear Cu(II)-Ln(III) (Ln = La, Gd or Tb) complexes He, F.; Tong, M.-L.; and Chen, X.-M., Inorg. Chem. 2005, 44, 8285-8292.
42. Supramolecular isomerism within three-dimensional 3-connnected nets: Unusual synthesis and characterization of trimorphic copper(I) 3,5-dimethyl-1,2,4-triazolate Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M., Dalton Trans. 2005, 3681-3685.
43. Temperature- or guest-induced drastic single-crystal-to-single-crystal transformations of a nanoporous coordination polymer Zhang, J.-P.; Lin, Y.-Y.; Zhang, W.-X.; Chen, X.-M., J. Am. Chem. Soc. 2005, 127, 14162-14163.
44. Infinite water chains trapped in organic framework constructed from melamine with 1,5-naphthalenedisulfonic acid via hydrogen bonds Zhang, X.-L.; Ye, B.-H.; Chen, X.-M., Cryst. Growth Des. 2005, 5, 1609-1616.
45. Syntheses, structures, photoluminescence and theoretical studies of a class of Be(II) compounds of aromatic N,O-chelate ligands Tong, Y.-P.; Zheng, S.-L.; Chen, X.-M., Inorg. Chem. 2005, 44, 4270-4275.
46. A solvothermally in-situ generated mixed-ligand approach for NLO-active metal–organic framework materials Wang, Y.-T.; Fan, H.-H.; Wang, H.-Z.; Chen, X.-M., Inorg. Chem. 2005, 44, 4148-4149.
47. Spin-canting and metamagnetism observed in a unique 3D homometallic molecular material constructed by interpenetration of two kinds of cobalt(II) coordination polymer sheets Zeng, M.-H.;Zhang, W.-X.; Sun, X.-Z.; Chen, X.-M., Angew. Chem. Int. Ed. 2005, 44, 3079-3082.
48. Well-resolved, new water morphologies obtained by modification of the hydrophilic/hydrophobic characters and shapes of the supporting surfaces Zhang, J.-P.; Huang, X.-C.; Lin, Y.-Y.; Chen, X.-M., Inorg. Chem. 2005, 44, 3146-3150.
49. Luminescent zigzag chains and triple-stranded helices of copper(I) 2-ethylimidazolate: Solvent polarity-induced supramolecular isomerism Huang, X.-C.; Zhang, J.-P.; Lin, Y.-Y.; Chen, X.-M., Chem. Commun. 2005, 2232–2234.
50. Copper(I) 1,2,4-triazolates and related complexes: Studies of the solvothermal ligand reactions, network topologies, and photoluminescence properties Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M., J. Am. Chem. Soc. 2005, 127, 5495-5506.
51. Effect of the size of aromatic chelate ligands on the frameworks of metal dicarboxylate polymers: from helical chains to 2-D networks Han, Z.-B.; Cheng, X.-N.; Chen, X.-M., Cryst. Growth Des. 2005, 5, 695–700.
52. Supramolecular architectures and helical water chains in cocrystals of melamine and aromatic carboxylic acids Zhang, X.-L.; Chen, X.-M., Cryst. Growth Des. 2005, 5, 617-622.
53. Molecular chairs, zippers, zigzag and helical chains: chemical enumeration of supramolecular isomerism based on a predesigned metal-organic building-block Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M., Chem. Commun. 2005, 1258–1260. (Hot Paper)
54. (Review Article) Metal-organic molecular architectures with 2,2’-bipyridyl-like and carboxylate ligands Ye, B.-H.; Tong, M.-L.; Chen, X.-M., Coord. Chem. Rev. 2005, 249, 545–565.
55. Controlled assembly of nanoscale heterometallic Cu12Ln6 Clusters (Ln = Gd or Nd) into 2D coordination polymers He, F.; Tong, M.-L.; Yu, X.-L.; Chen, X.-M., Inorg. Chem. 2005, 44, 559-565.
56. Homochiral crystallization of helical coordination chains bridged by achiral ligands: can it be controlled by the ligand structure? Wang, Y.-T.; Tong, M.-L., Fan, H.-H.; Wang, H.-Z.; Chen, X.-M., Dalton Trans. 2005, 424-426.(Hot Paper, Highlighted in Chemical Science)
57. Metallophilicity versus p-p interactions: Ligand-unsupported argentophilicity/cuprophilicity in oligomers-of-dimers [M2L2]n (M = Cu or Ag, L = tridentate ligand) Zhang, J.-P.; Wang, Y.-B.; Huang, X.-C.; Lin, Y.-Y.; Chen, X.-M., Chem. Eur. J. 2005, 11, 552-561.
2004
58. A new route to supramolecular isomers via molecular templating: nanosized molecular polygons of copper(I) 2-methylimidazolates Huang, X.-C.; Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2004, 126, 13218-13219.
59. (Cover Paper) Crystal-to-crystal transformations of a microporous metal-organic laminated framework triggered by guest exchange, dehydration and readsorption Zeng, M.-H.; Feng, X.-L.; Chen, X.-M., Dalton Trans. 2004, 2217-2223. (Highlighted in Chem. Sci.)
60. Syntheses, structures and photoluminescent properties of three silver(I) cluster-based coordination polymer with aromatic heterocycle carboxylates Yang, J.-H.; Zheng, S.-L.; Chen, X.-M., Cryst. Growth Des. 2004, 4, 831-836.
61. Syntheses, structures, and photoluminescence studies of [2:2] metallomacrocyclic silver(I) complexes with 1,3-bis(4,5-dihydro-1H-imidazol-2-yl)benzene Ren, C.-X.; Ye, B.-H.; He, F.; Cheng, L.; Chen, X.-M., CrystEngComm 2004, 6, 200-207.
62. A single-source approach to Bi2S3 and Sb2S3 nanorods via hydrothermal treatmentXie, G.; Qiao, Z.-P.; Zeng, M.-H.; Chen, X.-M.; Gao, S.-L., Cryst. Growth Des. 2004, 4, 513-516.
63. Two new mixed-valence Cu(I,II) imidazolate coordination polymers: Metal-valence tuning approach for new topologic structures Huang, X.-C.; Zhang, J.-P.; Lin, Y.-Y.; Chen, X.-M., Chem. Commun. 2004, 1100-1101.
64. Syntheses, structures, photoluminescence and theoretical studies of d metal complexes of 2,2'-dihydroxy-[1,1']binaphthalenyl-3,3'-dicarboxylate Zheng, S.-L.; Yang, J.-H.; Yu, X.-L.; Chen, X.-M., W.-T. Wong, Inorg. Chem. 2004, 43, 830-838.
65. Two unprecedented 3-connected three-dimensional networks of copper(I) triazolates: in-situ formation of ligands by cycloaddition of nitriles and ammonia Zhang, J.-P.; Zheng, S.-L.; Huang, X.-C.; Chen, X.-M., Angew. Chem. Int. Ed. 2004, 43, 206-209.
2003
66. (Review Article) Silver(I)-hexamethylenetetramine molecular architectures: From self-assembly to designed assembly Zheng, S.-L.; Tong, M.-L.; Chen, X.-M., Coord. Chem. Rev. 2003, 246, 185-202.
67. Syntheses, structures, photoluminescence and theoretical studies of a novel class of d metal complexes of 1H-[1,10]phenanthrolin-2-one Zheng, S.-L.; Zhang, J.-P.; Chen, X.-M.; Huang, Z.-L.; Lin, Z.-Y.; Wong, W.-T., Chem. Eur. J. 2003, 9, 3888-3896.
68. A novel, highly electrical conducting, single-component molecular material, [Ag2(ophen)2] (Hophen = 1H-[1,10]phenanthrolin-2-one) Zheng, S.-L.; Zhang, J.-P.; Wong, W.-T.; Chen, X.-M., J. Am. Chem. Soc. 2003, 125, 6882-6883.
2002
69. Double-stranded helices and molecular zippers assembled from single-stranded coordination polymers directed by supramolecular interactions Chen, X.-M.; Liu, G.-F., Chem. Eur. J. 2002, 8, 4811-4817.
70. Pseudo-polyrotaxane and b-sheet layer-based three-dimensional coordination polymers constructed with silver(I) salts and flexible pyridyl-type ligands Tong, M.-L.; Wu, Y.-M.; Ru, J.; Chen, X.-M., H.-C. Chang, Kitagawa, S., Inorg. Chem. 2002, 41, 4846-4848.
71. Metal cation-supported supramolecular crown ethers featuring hydrogen-bonded tetrameric unit of 2-hydroxy pyridines Tong, M.-L.; Lin, Z.-J.; Li, W.; Zheng, S.-L.; Chen, X.-M., Cryst. Growth Des. 2002, 2, 443-448.
72. Microwave-assisted elemental-direct-reaction route to nanocrystalline copper chalcogenides CuSe and Cu2Te Zhang, Y.; Qiao, Z.-P.; Chen, X.-M., J. Mater. Chem. 2002, 12, 2747-2748.
73. Syntheses, crystal structures and physical properties of dinuclear copper(I) and tetranuclear mixed valence copper(I,II) complexes with hydroxylated bipyridyl-like ligands Zhang, X.-M.; Tong, M.-L.; Gong, M.-L.; Lee, H.K.; Luo, L.; Li, J.-H.; Tong, Y.-X.; Chen, X.-M., Chem. Eur. J. 2002, 8, 3187-3194.
74. Interlocking of molecular rhombi into 2D polyrotaxane network via p-p interactions. Crystal structure of [Cu2(bpa)2(phen)2(H2O)]2×H2O (bpa = biphenyl-4,4¢-dicarboxylate, phen = 1,10-phenanthroline)Liu, G.-F.; Ye, B.-H.; Ling, Y.-H.; Chen, X.-M., Chem. Commun. 2002, 1442-1443.
75. A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions Tao, J.; Zhang, Y.; Tong, M.-L.; Chen, X.-M., Yuen, T.; Lin, C.L.; Huang, X.-Y.; Li, J., Chem. Commun. 2002, 1342-1343.
76. Synthesis, crystal structures and properties of six cubane-like transition metal complexes of di-2-pyridyl ketone in gem-diol form Tong, M.-L.; Lee, H.K.; Tong, Y.-X.; Zheng, S.-L.; Shi, J.-X.; Chen, X.-M., Dalton Trans. 2002, 1727-1734.
77. Hydroxylation of N-heterocycle ligands observed in two unusual mixed-valence CuI-CuII complexes Zhang, X.-M.; Tong, M.-L.; Chen, X.-M., Angew. Chem. Int. Ed. 2002, 41, 1029-1031.
78. One-pot monomer self-assembly route to thin coatings core/shell PbS/poly(methyl methacrylate) nanocomposites Qiao, Z.-P.; Xie, G.; Huang, J.-M.; Zhao, S.-Y.; Chen, X.-M., J. Mater. Chem. 2002, 12, 611–613.
79. Self-assembly of new three-dimensional molecular architectures constructed from silver(I)-hexamethylenetetramine layers with supramolecular interactions Zheng, S.-L.; Tong, M.-L.; Chen, X.-M.;Ng, S.W., Dalton Trans. 2002, 360-364.
2001
80. Syntheses, structures and properties of three novel coordination polymers of silver(I) aromatic dicarboxylates with hexamethylenetetramine exhibiting unique metal-p interaction Zheng, S.-L.; Tong, M.-L.; Tan, S.-D.; Wang, Y.; Shi, J.-X.; Tong, Y.-X.; Lee, H.K.; Chen, X.-M., Organometallics 2001, 20, 5319-5325.
81. Ferrimagnetic-like ordering in a unique three-dimensional coordination polymer featuring mixed azide/carboxylate-bridged trinuclear manganese(II) clusters as subunits Chen, H.-J.; Mao. Z.-W.; Gao, S.; Chen, X.-M. Chem. Commun. 2001, 2320-2321.
82. A blue photoluminescent three-dimensional coordination polymer constructed with helical [Zn3(µ3-OH)(µ2-OH)]¥ chains and mixed organic ligandsTao, J.; Tong, M.-L.; J.-X. Shi, Chen, X.-M., Inorg. Chem. 2001, 40, 6328-2330.
83. A novel supramolecular synthon for H-bonded coordination networks: syntheses and structures of extended 2-dimensional cadmium(II) arenedisulfonates Cai, J.-W.; Chen, C.-H.; Feng, X.-L.; Liao, C.-Z.; Chen, X.-M., Dalton Trans. 2001, 2370–2375.
84. The unique dual role of zinc atoms in a mixed zinc-vanadium phosphate [Zn(phen)Zn(VO)(PO4)2] Zhang, X.-M.; Tong, M.-L.; Feng, S.-H.; Chen, X.-M., Dalton Trans. 2001, 2069-2070.
85. Syntheses and structures of three two-dimensional silver(I)-hexamethylenetetramine coordination polymers with new topologic motifs Zheng, S.-L.; Tong, M.-L.; Zhu, H.-l.; Fang, Y.; Chen, X.-M., Dalton Trans. 2001, 2049-2053.
86. Toward designed assembly of microporous coordination networks constructed from the silver(I)-hexamethylenetetramine layers Zheng, S.-L.; Tong, M.-L.; Fu, R.-W.; Chen, X.-M., S.W. Ng, Inorg. Chem. 2001, 40, 3562-3569.
87. Hydrogen bonds induced change of geometry and crystallized form of copper(II) complexes: syntheses and crystal structure of copper(II) complexes with Schiff-base ligands containing two imidazolyl groupsLong, L.-S.; Cai, J.-W.; Ren, Y.-P.; Tong, Y.-X.; Chen, X.-M.; Ji, L.-N.; Huang, R.-B.; Zheng, L.-S., Dalton Trans. 2001, 845-849.
88. A novel polycatenated double-layered hybrid organic-inorganic material constructed from [Zn2(tp)(4,4¢-bpy)]n layers and V4O12pillars Tao, J.; Zhang, X.-M.; Tong, M.-L.; Chen, X.-M., Dalton Trans.2001,770-771.
89. Syntheses and structures of six chain-, ladder- and grid-like coordination polymers constructed from m-hexamethylenetetramine and silver salts Zheng, S.-L.; Tong, M.-L.; Chen, X.-M., Dalton Trans. 2001, 586-592.
90. Syntheses and crystal structures of four metal-organic coordination networks constructed form cadmium(II) thiocyanate and nicotinic derivatives with hydrogen bonds Yang, G.; Zhu, H.-G.; Liang, B.-H.; Chen, X.-M., Dalton Trans. 2001, 580-585.
91. Syntheses and crystal structures of five two-dimensional networks constructed from staircase-like silver(I) thiocyanate chains and bridging polyamines Ren, C.-X.; Zhu, H.-L.; Yang G.; Chen, X.-M., Dalton Trans. 2001, 85-90.
2000
92. Influence of ligand backbones and counter ions on structures of helical silver(I) complexes with di-Schiff bases derived from phthalaldehydes and diamine Zhu, H.-L.; Tong, Y.-X.; Chen, X.-M., J. Chem. Soc. , Dalton Trans. 2000, 4182-4186.
93. Hydrothermal synthesis and crystal structures of [M(tp)(4,4’-bipy)] (M = Co(II), Cd(II) and Zn(II)): Three-dimensional coordination frameworks constructed with mixed terephthalate (tp) and 4,4’ bipyridine (4,4’-bipy) ligands Tao, J.; Tong, M.-L.; Chen, X.-M., J. Chem. Soc. , Dalton Trans. 2000, 3669-3674.
94. Blue photoluminescent zinc co-ordination polymers with supertetranuclear coresTao, J.; Tong M.-L.; Shi, J.-X.; Chen, X.-M., Ng, S.W., Chem. Commun. 2000, 2043-2044.
95. An octanuclear copper(II) complex self-assembled with divalent gem-diol form anion of di-2-pyridyl ketone (dpd-2H) and 2-hydroxylpyridine. Synthesis, crystal structure and properties of [Cu8(dpd-2H)4(m2-O2CMe)4{2-(OH)C5H4N}4](ClO4)4×4H2O Tong, M.-L.; Lee, H. K.; Tong, Y.-X.; Chen, X.-M.; Mak, T.C.W., Inorg. Chem. 2000, 39, 4666-4669.
96. Self-assembly of two- and three-dimensional coordination networks with hexamethylenetetramine and different small simple silver(I) salts Tong, M.-L.; Zheng, S.-L.; Chen, X.-M., Chem. Eur. J. 2000, 6, 3729-3638.
97. Hydrothermal synthesis and crystal structures of two bimetallic chain-like and cluster complexes [{Co(phen)2}2V6O17]n and [{Cu(phen)2}4V10O29]×6H2O Zhang, X.-M.; Tong, M.-L.; Chen, X.-M., Chem. Commun. 2000, 1817-1818.
98. Organic-inorganic hybrid materials assembled through weak intermolecular interactions. Synthesis, structures and non-linear optical properties of [4,4’-bipyH2][M(NCS)4] (M = Mn, Co and Zn; 4,4’-bipy = 4,4’-bipyridine) Chen, H.-J.; Zhang, L.-Z.; Cai, Z.-G.; Yang, G.; Chen, X.-M., J. Chem. Soc. Dalton Trans. 2000, 2463-2467.
99. Influence of the counter-ions and ligands on structures of silver(I) helicates with di-Schiff bases containing imidazole groups Yang, S.-P.; Chen, X.-M.; L.-N. Ji, J. Chem. Soc., Dalton Trans. 2000, 2337-2344.
100. Molecular ladders with multiple interpenetration of the lateral arms into the squares of adjacent ladders observed for [M2(4,4’-bpy)3(H2O)2(phba)2](NO3)2×4H2O (M = Cu2+ or Co ; 4,4’-bpy = 4,4’-bipyridine; phba = 4-hydroxybenzoate) Tong, M.-L.; Chen, H.-J.; Chen, X.-M., Inorg. Chem. 2000, 39, 2235-2238.
101. Anionic and neutral metal-4,4’-bipyridine networks. Synthesis, structures and thermal properties of one- and three-dimensional coordination polymers constructed by metal salts and 4,4’-bipyridineTong, M.-L.; Chen, X.-M., CrystEngCom 2000, 1.
1999
102. A novel three-dimensional triangular organic-inorganic hybrid network self-assembled by mononuclear [Mn(4,4’-bipyridine)2(H2O)4] cations and rich solvate 4,4’-bipyridine molecules throughhydrogen- bonding and p-p interactions Tong, M.-L.; Lee, H. K.; Chen, X.-M.; Huang, R.-B.; Mak, T.C.W., J. Chem. Soc. Dalton Trans. 1999, 3657-3659.
103. Self-assembled three-dimensional coordination polymers with unusual ligand-unsupported Ag-Ag bonds: Syntheses, structures and luminescent properties Tong, M.-L.; Chen, X.-M.; Ye, B.-H.; Ji, L.-N.Angew. Chem. Int. Ed. 1999, 38, 2237-2240.
104. Synthesis and structures of carboxylate-bridged polynuclear copper(II)-lanthanide(III) complexes [CuLn(pyridinioacetate)5(H2O)5](ClO4)5·2H2O and [Cu3Nd2(pyridinioacetate)10(NO3)2(H2O)8](ClO48·4H2O Yang, Y.-Y.; Wu, Y.-L.; Long, L.-S.; Chen, X.-M., J. Chem. Soc., Dalton Trans. 1999, 2005-2008.
105. Synthesis, crystal structures and properties of copper(II) complexes of Schiff base derivativescontaining imidazole and b-alanine groups Long, L.-S.; Yang, S.-P.; Tong, Y.-X.; Mao, Z.-W.; Chen,X.-M.; Ji, L.-N. J. Chem. Soc., Dalton Trans. 1999, 1999-2004.
106. Two- and three-dimensional non-interpenetrating open-networks self-assembled by m4 hexamethylene-tetramine (hmt). Syntheses and structures of [Ag2(m4-hmt)(SO4)(H2O)]×4H2O and [Ag2(m4-hmt)(m2-O2CMe)](MeCO2)×4.5H2O Tong, M.-L.; Zheng, S.-L.; Chen, X.-M., Chem. Commun. 1999, 561-562.
1998
107. Synthesis, structures and magnetic properties of carboxylate-bridged tetranuclear copper(II)-lanthanoid(III) complexes [Cu2Ln2(betaine)10(H2O)8](ClO4)10·2H2O and [Cu2Ln2(betaine)12(ClO4)2](ClO4)8 Chen, X.-M.; Wu, Y.-L.; Yang, Y.-Y; Aubin, S.M.J.; Hendrickson, D.N. Inorg. Chem. 1998, 37, 6186-6191.
108. Helical silver(I)-2,4'-bipyridine chains organized into 2-D networks by metal-counterion or metal- metal bonding. Structures of [Ag(2,4'-bipyridine)]X (X = NO or ClO) Tong, M.-L.; Chen, X.-M.; Ye, B.-H.;Ng, S.W., Inorg. Chem. 1998, 37, 5278-5281.
109. Clathration of two-dimensional coordination polymers: Syntheses and structures of [M(4,4'-bpy)2(H2O)2](ClO4)2(2,4'-bpy)2×H2O and [Cu(4,4'-bpy)2(H2O)2](ClO4)4×(4,4'-H2bpy) (M = Cd, Zn, bpy = bipyridine)Tong, M.-L.; Ye, B.-H.; Cai, J.-W.; Chen, X.-M., Ng, S.W., Inorg. Chem. 1998, 37, 2645-2650.
110. A novel two-dimensional rectangular network. Synthesis and structure of {[Cu(4,4'-bpy)(pyz)(H2O)2](PF6)2}n (4,4'-bpy = 4,4'-bipyridine, pyz = pyrazine) Tong, M.-L.; Yu, X.-L.; Chen, X.-M.; Mak, T.C.W., J. Chem. Soc., Dalton Trans. 1998, 5-6.
1994 - 1997
111) The first metal-encapsulating star polysulphoxide incorporating 2-amino-1,3,4-thiadiazoleYang, C.; Chen, X.-M.; Lu, X.-Q.; Zhou, Q.-H.; Yang, Y.-S., J. Chem. Soc., Chem. Commun. 1997, 2041-2042.
112. Model complexes for the carboxylate-histidine-metal triad systems in metalloenzymes. Synthesis, crystal structures and spectroscopic properties of [M(Him)2(O2CMe)2] (M = ZnII or CoII, Him = imidazole). Chen, X.-M.; Ye, B.-H.; Huang, X.-C.; Xu, Z.-T., J. Chem. Soc., Dalton Trans. 1996, 3465-3468.
113. Novel octadecanuclear copper(II)-lanthanoid(III) clusters. Synthesis and structures of [Cu12Ln6(m3-OH)24(O2CCH2CH2NC5H5)12(H2O)16(m12-ClO4)](ClO4)17·16H2O (Ln = Gd or Sm) Chen, X.-M.; Wu, Y.-L.; Tong, Y.-X.; Huang, X.-Y., J. Chem. Soc., Dalton Trans. 1996, 2443-2448.
114. Synthesis, crystal structure and luminescence properties of a europium(III) complex with a new planar aromatic tridentate N3 ligand Yang, C.; Chen, X.-M.; Zhang, W.-H.; Chen, J.; Yang, Y.-S.; Gong, M.-L., J. Chem. Soc., Dalton Trans. 1996, 1767-1768.
115. Synthesis and structure of a novel carboxylate-bridged heterometallic copper(II)-gadolinium(III) complex Chen, X.-M.; Tong, M.-L.; Wu, Y.-L.; Luo, Y.-J., J. Chem. Soc., Dalton Trans. 1996, 2181-2182.
116. Synthesis, structure and magnetic properties of a singly carboxylato-bridged dinuclear Mn(II) complex Chen, X.-M.; Tong, Y.-X.; Xu, Z.-T.; Mak, T.C.W., J. Chem. Soc., Dalton Trans. 1995, 4001-4004.
117. Polynuclear Cu12-M6 (M = Y, Nd or Gd) complexes encapsulating a ClO4– anion: [Cu12M6(OH)24(pyb)12(H2O)18(ClO4)](ClO4)17·nH2O (pyb = pyridine betaine) Chen, X.-M.; Aubin, S.M.J.; Wu, Y.-L.; Yang, Y.-S.; Mak, T.C.W.; Hendrickson, D.N., J. Am. Chem. Soc. 1995, 117, 9600-9601.
118. A model complex for the carboxylate-histidine-zinc system in zinc enzymes. Crystal structure of [Zn(Him)2(MeCO2)2] (Him = imidazole) Chen, X.-M.; Xu, Z.-T.; Huang, X.-C., J. Chem. Soc., Dalton Trans. 1994, 2331-2332.
119. A dinuclear zinc complex of biological relevance. Crystal structure of [Zn2(bpy)2(MeCO2)3]ClO4 Chen, X.-M.; Tong, Y.-X.; Mak, T.C.W., Inorg. Chem. 1994, 33, 4586-4588.
