科研成就
從事有機/聚合物光電功能材料(發光材料和光伏材料)及其分子器件的研究。先後主持國家、省部級科研項目10餘項,包括國家自然科學基金重大研究計畫培育項目和面上項目6項。主持省級教學改革項目2項。在有機/聚合物發光材料、光伏材料及其分子器件等國際前沿科學領域中已取得一些有國際影響的研究成果。以署名第一或通訊聯繫人在Advanced Energy Materials, Journal of Materials Chemistry, Chemical Communication, Macromolecules等國內外重要學術刊物上發表SCI學術論文98篇。
2009年獲廣東省自然科學獎一等獎(排名第9),2010年獲湖南省自然科學獎二等獎(排名第1),2013年獲湖南省教學成果二等獎(排名第1)。獲中國授權發明專利9項(排名第1)。
指導研究生獲歐盟“瑪麗.居里”獎學金1人、寶鋼教育獎-優秀學生獎1人、湖南省優秀博士論文1人、研究生國家獎學金3人、湘潭大學研究生校長獎特等獎3人、校長獎優秀獎2人。
主講課程
有機化學,有機化學實驗,現代有機合成實驗,有機催化,有機功能材料。
人物經歷
學習經歷
1982/09至1986/06,理學學士,化學專業,湘潭大學化學系
1994/09至1995/09,有機化學碩士學位課程學習,湘潭大學化學系
1997/09至2000/06,理學博士,有機化學,四川大學化學學院
2006/02至2007/02,英國Sheffield大學訪問學者
工作經歷
1986/06至1994/04,湘潭大學技術科學研究所,助理工程師、工程師,室副主任
1994/04至1997/09,湘潭大學化學系,講師
1997/09至2002/08,湘潭大學化學化工學院,副教授,碩士生導師
2000/10至2002/10,華南理工大學聚合物光電材料與器件研究所,博士後
2002/10至2007/12,湘潭大學化學學院,副院長,教授,博士生導師
2007/12至2013/09,湘潭大學化學學院,院長,教授,博士生導師
2013/10至2015/12,湘潭大學研究生院,院長,教授,博士生導師
2016/01至今, 常州大學材料科學與工程學院,教授,博士生導師
研究方向
有機/聚合物光電功能材料及其分子器件
獲獎情況
1. 有機/高分子電致發光材料及其發光器件的研究,湖南省自然科學獎(二等獎,證書號20102046-Z2-014-R01),2010-12,排名第一。
2. 廣東省科學技術獎(一等獎,證書號A02-0-1-R09),2009-07,排名第九。
3. 寶鋼教育獎(寶鋼優秀教師獎,證書號201310238),2013-11。
4. 國務院政府特殊津貼(證書號2014018039),2015-01。
5. 發揮專業特色和平台優勢,創新培養機制,培養化學創新創業人才,湖南省教學成果獎(二等獎,證書號2012069),2013-12,排名第一。
6. 湖南省優秀博士論文指導教師(證書號20151042),2015
科研項目
1. “先進光電與超分子功能材料”創新團隊發展計畫培育團隊(1337304),2014.01-2016.12,團隊負責人
2. “先進能量轉換存儲材料及其器件” 湖南省自然科學基金創新研究群體(12JJ7002),2012.06-2015.06,群體負責人
3. 國家自然科學基金(51473140):供體-受體型環金屬鉑(II)配合物近紅外電致發光材料的分子設計、合成及其性能研究,2015.01-2018.12,主持
4. 國家自然科學基金重大研究計畫培育項目(91233112):D-A-A 和D-A-Ar 線型和星型有機供體材料的分子構築、合成及其光伏性能的研究,2013.01-2015.12,主持(結題)
5. 國家自然科學基金(21172187):基於多元供體受體的線型和星型有機光伏材料的合成及其溶液加工型有機太陽能電池的性能研究,2012.01-2015.12,主持(結題)
授權專利
朱衛國, 張友明, 譚華, 陶強, 賀克奇, 劉煜, 王亞飛. 一種D(A-Ar)n型化合物及其套用,中國發明專利,ZL201310349158.5,授權時間2015-10-07.
朱衛國, 於俊婷, 譚華, 王亞飛, 劉煜, 朱美香. 一種D-A-A型C^N配體化合物及其C^N環金屬鉑配合物和套用,中國發明專利,ZL2013 1029 1798.5,授權時間2015-12-02.
朱衛國, 石丹艷, 劉煜, 王亞飛, 朱美香. 樹枝狀三核環金屬鉑配合物電致磷光材料及其在聚合物電致白光器件中的套用. 中國發明專利,申請號: ZL 201110430975.4. 授權時間2014-04-16.
朱衛國, 王亞飛, 劉煜, 朱美香. 一類二(吡啶苯基)芴衍生物及其雙核環金屬鉑配合物液晶偏振發光材料. 中國發明專利,ZL 2010 10515850.7. 授權時間2012-05-02.
朱衛國, 王亞飛, 劉煜, 朱美香. 液晶偏振異質環金屬鉑配合物發光材料. 中國發明專利,ZL 20091044088.6. 授權時間2011-10-15.
朱衛國, 吳秀剛, 胡崢勇, 劉煜. 一類雙核環金屬鉑配合物近紅外發光材料及其套用. 中國發明專利, ZL 200910044087.1. 授權時間2011-09-14.
朱衛國, 胡崢勇, 羅翠萍, 朱美香. 異喹啉基三芳胺環金屬配合物及其套用. 中國發明專利, ZL 200610032479.2, 授權時間2009-07-22.
朱衛國, 朱美香, 甘泉, 楊玉萍. 功能化吡啶甲酸及其環金屬銥配合物的製備和套用. 中國發明專利, ZL 200610032480.5, 授權時間 2009-03-11.
朱衛國, 劉煜, 羅翠萍, 胡崢勇, 朱美香. 基於功能化鄰菲羅啉配體的有機銪配合物及其電致發光器件. 中國發明專利, ZL 200610032550.7, 授權時間2008-12-3.
朱衛國, 劉堅, 羅翠萍, 胡崢勇, 劉煜, 朱美香. 一種含三芳胺功能基的環金屬鉑配合物電致磷光材料. 中國發明專利, ZL 200510032482.XA. 授權時間2007-06-20.
1.朱衛國, 張友明, 譚華, 陶強, 賀克奇, 劉煜, 王亞飛. 一種D(A-Ar)n型化合物及其套用,中國發明專利,ZL201310349158.5,授權時間2015-10-07.
2.朱衛國, 於俊婷, 譚華, 王亞飛, 劉煜, 朱美香. 一種D-A-A型C^N配體化合物及其C^N環金屬鉑配合物和套用,中國發明專利,ZL2013 1029 1798.5,授權時間2015-12-02.
3.朱衛國, 石丹艷, 劉煜, 王亞飛, 朱美香. 樹枝狀三核環金屬鉑配合物電致磷光材料及其在聚合物電致白光器件中的套用. 中國發明專利,申請號: ZL 201110430975.4. 授權時間2014-04-16.
4.朱衛國, 王亞飛, 劉煜, 朱美香. 一類二(吡啶苯基)芴衍生物及其雙核環金屬鉑配合物液晶偏振發光材料. 中國發明專利,ZL 2010 10515850.7. 授權時間2012-05-02.
5.朱衛國, 王亞飛, 劉煜, 朱美香. 液晶偏振異質環金屬鉑配合物發光材料. 中國發明專利,ZL 20091044088.6. 授權時間2011-10-15.
6.朱衛國, 吳秀剛, 胡崢勇, 劉煜. 一類雙核環金屬鉑配合物近紅外發光材料及其套用. 中國發明專利, ZL 200910044087.1. 授權時間2011-09-14.
7.朱衛國, 胡崢勇, 羅翠萍, 朱美香. 異喹啉基三芳胺環金屬配合物及其套用. 中國發明專利, ZL 200610032479.2, 授權時間2009-07-22.
8.朱衛國, 朱美香, 甘泉, 楊玉萍. 功能化吡啶甲酸及其環金屬銥配合物的製備和套用. 中國發明專利, ZL 200610032480.5, 授權時間 2009-03-11.
9.朱衛國, 劉煜, 羅翠萍, 胡崢勇, 朱美香. 基於功能化鄰菲羅啉配體的有機銪配合物及其電致發光器件. 中國發明專利, ZL 200610032550.7, 授權時間2008-12-3.
10.朱衛國, 劉堅, 羅翠萍, 胡崢勇, 劉煜, 朱美香. 一種含三芳胺功能基的環金屬鉑配合物電致磷光材料. 中國發明專利, ZL 200510032482.XA. 授權時間2007-06-20.
論文發表
一、 線型有機小分子光伏材料
1)Jianhua Chen, Linrui Duan, Manjun Xiao, Qiong Wang, Bin Liu, Hao Xia, Renqiang Yang* and Weiguo Zhu*. Tuning the central fused ring and terminal units to improve the photovoltaic performance of Ar(A–D) type small molecules in solution-processed organic solar cells. Journal of Materials Chemistry A, 2016, DOI: 10.1039/c6ta00416d. IF = 8.262.
2)Xiongwei Duan, Manjun Xiao,Jianhua Chen,Xiangdong Wang, Wenhong Peng, Linrui Duan,Hua Tan, Gangtie Lei, Renqiang Yang,*, and Weiguo Zhu*. Improving photovoltaic performance of the linear A-Ar-A-type small molecules with diketopyrropyrrole arms by tuning the linkage position of the anthracene core. ACS Applied Materials & Interfaces, 2015, 33, 18292–18299. IF = 7.145.
3) Jianhua Chen, Manjun Xiao, Linrui Duan, Qiong Wang, Hua Tan, Ning Su, Yu Liu, Renqiang Yang* and Weiguo Zhu*, Benzodi(pyridothiophene): a novel acceptor unit for application in A1–A–A1 type photovoltaic small molecules, Physical Chemistry Chemical Physics, 2016, 18, 1507-1515. IF = 4.449.
4)Qiang Tao, Linrui Duan, Wenjing Xiong, Gongyue Huang, Pu Wang, Hua Tan,* Yafei Wang, Renqiang Yang* and Weiguo Zhu*, D(A-A') architecture: an efficient strategy to improve photovoltaic performance of small molecules for solution-processed organic solar cells. Dyes and Pigments, 2016, 10.1016/j.dyepig. IF = 4.055.
5)Qunping Fan, Min Li, Pingao yang, Yu Liu*, Manjun Xiao, Xiangdong Wang, Hua Tan, Yafei Wang, Renqiang Yang*, Weiguo Zhu*. Acceptor-donor-acceptor small molecules containing benzo [1,2-b:4,5-b']dithiophene and rhodanine units for solution processed organic solar cells. Dyes and Pigments, 2015, 116, 13-19. IF = 4.055.
二、星型有機小分子光伏材料
6) Pei Zhou, Dongfeng Dang, Manjun Xiao, Qiong Wang, Juan Zhong, Hua Tan, Yong Pei, Renqiang Yang* and Weiguo Zhu*. Improved photovoltaic performance of star-shaped molecules with a triphenylamine core by tuning the substituted position of the carbazolyl unit at the terminal. Journal of Materials Chemistry A, 2015, 3, 10883-10889. IF = 8.262.
7) Pei Zhou, Dongfeng Dang, Qiong Wang, Xiongwei Duan, Manjun Xiao, Qiang Tao, Hua Tan, Renqiang Yang, Weiguo Zhu*. To enhance photovoltaic performance of the triphenylamine based star-shaped molecules by tuning the moiety sequence of their arms in organic solar cells. Journal of Materials Chemistry A, 2015, 3, 13568–13576. IF = 8.262.
8) Youming Zhang, Xichang Bao*, Manjun Xiao, Hua Tan*, Qiang Tao, Yafei Wang, Yu Liu, Renqiang Yang* and Weiguo Zhu*. Significantly improved photovoltaic performance of the triangular-spiral TPA(DPP-PN)by appending planar phenanthrene units into the molecular terminals. Journal of Materials Chemistry A, 2015, 3, 886-893. IF = 8.262.
三、染料敏化分子
9) Yafei Wang*, Chuncheng Yang, Jue Chen, Hongrui Qi, Jianli Hua, Yu Liu, Etienne Baranoff*, Hua Tan, Jiang Fan, Weiguo Zhu*. Influence of the donor size in panchromatic D-π-A-π-A dyes bearing 5-phenyl-5H-dibenzo[b,f] azepine units for dye-sensitized solar cells. Dyes and Pigments, 2016, 127, 204-212. 一區, IF = 4.055.
四、一維聚合物光伏材料
10) Dongfeng Dang, Weichao Chen, Scott Himmelberger, Qiang Tao, Angelica Lundin, Renqiang Yang,* Weiguo Zhu*, Alberto Salleo, Christian Müller, and Ergang Wang*. Enhanced photo- voltaic performance of indacenodithiophene-quinoxaline copolymers by side-chain modulation. Advanced Energy Materials. 2014, 4, 1400680. IF = 15.23.
11) Dongfeng Dang*, Pei Zhou, Linrui Duan, Xichang Bao, Renqiang Yang* and Weiguo Zhu*. An efficient method to achieve a balanced open circuit voltage and short circuit current density in polymer solar cells, Journal of Materials Chemistry A, 2016, 4, 8291-8297. IF = 8.262.
12) Dongfeng Dang, Weichao Chen, Renqiang Yang*, Weiguo Zhu*, Wendimagegn Mammo and Ergang Wang*. Fluorine substitution enhanced photovoltaic performance of a D-A1-D-A2 copolymer. Chemical Communication, 2013, 49, 9335-9337. IF = 6.567.
13) Qiang Tao, Yuxin Xia, Xiaofeng Xu, Svante Hedström, Olof Bac̈ke, DavidI.James, Petter Persson Eva Olsson, Olle Inganas̈, Lintao Hou,* WeiguoZhu,* and ErgangWang*. D-A- D-A copolymers with extended donor segments for efficient polymer solar cells. Macromolecules, 2015, 48, 1009−1016. IF = 5.554.
14) Jiamin Cao, Wei Zhang, Zuo Xiao, Lingyan Liao, Weiguo Zhu*, Qiqun Zuo, Liming Ding*. Synthesis and photovoltaic properties of low band gap polymers containing benzo[1,2-b:4,5-c¢] dithiophene-4,8-dione. Macromolecules, 2012, 45, 1710−1714. IF = 5.554.
15) Qunping Fan, Yu Liu*, Manjun Xiao, Wenyan Su, Huishan Gao, Jianhua Chen, Hua Tan, Yafei Wang, Renqiang Yang* and Weiguo Zhu*. Enhancing the photovoltaic properties of terpolymers containing benzo[1,2-b:4,5-b′]dithiophene, phenanthro[4,5-abc]phenazine and benzo[c][1,2,5]thiadiazole by changing the substituents. Journal of Materials Chemistry C, 2015, 3, 6240-6248. 一區, IF = 5.066.
16) Wei Zhang, Jiamin Cao, Ying Liu, Zuo Xiao*, Weiguo Zhu*, Qiqun Zuo, Liming Ding *. Using cyclopenta[2,1-b:3,4-c¢]dithiophene-4-one as a building block for low-bandgap conjugat- ed copolymers applied in solar cells. Macromolecular Rapid Communications, 2012, 33, 1574−1579. IF = 4.638.
17) Pei Zhou, Jiang Fan, Dongfeng Dang, Junwei Shi, Xiangdong Wang, Wenhong Peng, Hua Tan, Yafei Wang,* Yu Liu, Weiguo Zhu*. Enhanced photovoltaic properties of di(dodecylthio- phene)- alt-2,3-di(3-octoxylphenyl)-5,8-dithieno[3,2-b]thiophene-6,7-difluoroquinoxaline copolymer by fluorination. Dyes and Pigments, 2015, 113, 312–317. IF = 4.055.
18) Dongfeng Dang, Pei Zhou, Qing Peng, Keqi He, Haigang Jiang, Pingao Yang, Hua Tan, Yong Pei, Yu Liu,* Gangtie Lei, Weiguo Zhu*. Improved photovoltaic performance of two- dimensional low band-gap conjugated polymers with thieno[3,2-b]thiophene and diketo- pyrrolo pyrrole units by altering pendent position of conjugated side chain. Dyes and Pigments, 2014, 109, 6-12. IF = 4.055.
五、二維聚合物光伏材料
19) Hua Tan, Xianping Deng, Junting Yu, Baofeng Zhao, Yafei Wang, Yu Liu, Weiguo Zhu*, Hongbin Wu*, and Yong Cao*. A novel benzo[1,2-b:4,5-b']dithiophene-based conjugated polymer with a pendant diketopyrrolopyrrole unit for high-performance solar cells. Macro- molecules, 2013, 46, 113–118. IF = 5.554.
20) Qunping Fan, Manjun Xiao, Yu Liu*, Wenyan Su, Huishan Gao, Hua Tan, Yafei Wang, Gangtie Lei, Renqiang Yang* and Weiguo Zhu*. Improved photovoltaic performance of a 2D-conjugated benzodithiophene-based polymer by the side chain engineering of quino- xaline. Polymer Chemistry, 2015, 6, 4290-4298. IF = 5.687.
21) Pei Zhou, Dongfeng Dang, Jiang Fan, Wenjing Xiong, Chunchen Yang, Hua Tan, Yafei Wang*, Yu Liu, Weiguo Zhu*. Increasing thiophene spacers between thieno[3,2-b] thiophene and benzothiadiazole units in backbone to enhance photovoltaic performance for their 2-D polymers. Dyes and Pigments, 2015, 112, 99-104. IF = 4.055.
六、有機近紅外發光材料及其及其聚合物電致發光器件
22) Wenjing Xiong , Fanyuan Meng, Hua Tan,* Yafei Wang, Pu Wang, Youming Zhang, Qiang Tao, and Shijian Su,* Weiguo Zhu*, Di-nuclear platinum complexes containing aryl-isoquinoline and oxadiazole-thiol with an efficiency over 8.8%: In-depth investiga- tion on relationship between the molecular structure and near-infrared electroluminescent properties in PLEDs. Journal of Materials Chemistry C , 2016,4, 6007 - 6015.IF = 5.066.
23 ) Youming Zhang, Fanyuan Meng, Jian-Hong Tang, Yafei Wang, Caifa You, Hua Tan, Yu Liu, Yu-Wu Zhong, Shijian Su and Weiguo Zhu*. Achieving near-infrared emission in platinum(II) complexes by using an extended donor–acceptortype ligand. Dalton Trans. 2016, 45, 5071-5080. IF = 4.177.
24 ) Ning Su, Fanyuan Meng, Jianhua Chen, Yafei Wang, Hua Tan, Shijian Su, Weiguo Zhu*. Near-infrared emitting pyrazole-bridged binuclear platinum complexes: Synthesis, photophysical and electroluminescent properties in PLEDs. Dyes and Pigments. 2016, 128 68-74. IF = 4.055.
25 ) Junting Yu, Keqi He, Yanhu Li, Hua Tan, Meixiang Zhu, Yafei Wang, Yu Liu, Weiguo Zhu*, Hongbin Wu*. A novel near-infrared-emitting cyclometalated platinum (II) complex with donoreacceptoreacceptor chromophores. Dyes and Pigments, 2014, 107, 146-152. IF = 4.055.
七、液晶偏振磷光材料
26 ) Yafei Wang, Qing Chen, Yanhu Li, Yu Liu, Hua Tan, Junting Yu, Meixiang Zhu, Hongbin Wu, Weiguo Zhu*, Yong Cao. Highly dichroic metallomesogen of dinuclear platinum complex: synthesis, liquid crystal and photophysical properties. Journal of Physical Chemistry. C, 2012, 116, 5908−5914. IF = 4.509.
27 ) Yafei Wang, Junwei Shi, Jianhua Chen, Weiguo Zhu* and Etienne Baranoff. Recent progress in luminescent liquid crystal materials: design, properties and application for linearly polarised emission. Journal of Materials Chemistry C, 2015, 3, 7993-8005. IF = 5.066.
28 ) Yafei Wang, Yu Liu*, Jian Luo, Hongrui Qi, Xiaoshuang Li, Meijun Nin, Ming Liu, Danyan Shi, Weiguo Zhu*, Yong Cao*. Metallomesogens based on platinum (II) complexes: synthesis, luminescence and polarized emission. Dalton Transactions, 2011, 40,5046- 5051.IF = 4.177.
八、單分子有機電致白光材料及其聚合物白光器件
29 ) Yafei Wang, Ning Sun, Basile F. E. Curchod, Louise Male, Dongge Ma, Jiang Fan, Yu Liu, Weiguo Zhu * and Etienne Baranoff. Tuning the oxidation potential of 2-phenylpyridine-based iridium complexes to improve the performance of bluish and white OLEDs. J. Mater. Chem. C, 2016, DOI:10.1039/C5TC02355F. IF = 5.066.
30 ) Danyan Shi, Yafei Wang*, Yu Liu, Zhiyong Zhang, Jian Luo, Juan He, Qing Chen, Gangtie Lei, and Weiguo Zhu*. Star-shaped trinuclear cyclometalated platinum(II) complexes as single-component emitters in white-emitting PLEDs. Chemistry An Asian Journal, 2012, 7, 2096-2101.IF = 4.592.
31 ) Xiaoshuang Li, Yu Liu, Jian Luo, Zhiyong Zhang, Danyan Shi, Qing Chen, Yafei Wang,* Juan He, Jianming Li, Gangtie Lei, Weiguo Zhu*. Synthesis and optoelectronic properties of a heterobimetallic Pt(II)–Ir(III) complex used as a single-component emitter in white PLEDs. Dalton Transactions, 2012, 41, 2972-2978. IF = 4.177.
32 ) Aihui Liang, Yanhu Li, Weiguo Zhu*, Yafei Wang, Fei Huang, Hongbin Wu, Yong Cao. Novel cyclometalated platinum (II) complex containing carrier-transporting groups: synthe -sis, luminescence and application in single-dopant white PLEDs. Dyes and Pigments, 2013, 96, 732-737. IF = 4.055.
33 ) Yafei Wang, Yu Liu*, Zhiyong Zhang, Jian Luo, Danyan Shi, Hua Tan, Gangtie Lei, Meixiang Zhu, Weiguo Zhu*, Yong Cao*. Single-layer white polymer light emitting diodes based on iridium (III) complex containing alkyltrifluorene picolinic acid. Dyes and Pigments, 2011, 91, 495-500. IF = 4.055.
九、三基色有機/聚合物磷光材料及其聚合物電致發光器件
34 ) Jian Luo, Yu Liu, Qing Chen, Danyan Shi, Ying Huang, Junting Yu, Yafei Wang*, Zhiyong Zhang, Gangtie Lei, Weiguo Zhu*. Synthesis, optoelectronic properties of a dinuclear platinum (II) complex containing a binary cyclometalated ligand in the single-emissive-layer PLEDs. Dalton Transactions, 2013, 42, 1231-1237. IF = 4.177.
35 ) Yu Liu, Yafei Wang, Haipeng Guo, Meixiang Zhu, Chun Li, Junbiao Peng, Weiguo Zhu*, Yong Cao*. Synthesis and optoelectronic characterization of a monochromic red-emitting europium (III) complex containing triphenylamine-functionalized phenanthroline. Journal of Physical Chemistry. C, 2011, 115, 4209–4216. IF = 4.509.
36)Jian Luo, Yu Liu, Danyan Shi, Yafei Wang*, Zhiyong Zhang, Junting Yu, Gangtie Lei, Qing Chen, Jianming Li, Xianping Deng, Weiguo Zhu*. Synthesis, optoelectronic properties of carbazole-modified platinum (II) complexes in polymer light-emitting devices. Dalton Transactions, 2012, 41, 1074-1081. IF = 4.177.
37 ) Yu Liu*, Jianyu Wang, Yafei Wang, Zhiyong Zhang, Meixiang Zhu, Gangtie Lei, Weiguo Zhu*. Bipolar-transporting dinuclear europium (III) complexes involving carbazole and oxadiazole units: Synthesis, photophysical and electroluminescent properties. Dyes and Pigments, 2012, 95, 322-329. IF = 4.055.
38 ) Zhengyong Hu, Yafei Wang, Danyan Shi, Hua Tan, Xiaoshuang Li, Lei Wang, Weiguo Zhu*, Yong Cao. Highly-efficiency red-emitting platinum (II) complexes containing 4¢-diaryl amino-1-phenylisoquinoline ligands in polymer light-emitting diodes: Synthesis, structure, photoelectron and electroluminescence. Dyes and Pigments, 2010, 86, 166-173. IF = 4.055.