人物簡介
男,1963年5月生於山東,中共黨員,理學博士,教授,博士研究生導師,享受國務院政府特殊津貼,浙江省高等學校特聘教授(錢江學者)、浙江省“151”人才第一層次、山東省千名知名技術專家。美國科學促進會會員、美國化學會會員、中國化學會會員。1984年畢業於山東大學化學系,獲理學學士學位,同年考取山東大學化學系高分子專業碩士研究生,師從於著名有機矽專家杜作棟教授,1987年獲理學碩士學位並留在山東大學新材料研究所工作;1992年考取山東大學化學學院物理化學專業的博士研究生,師從於中國科學院院士、著名理論化學家鄧叢豪教授,1996年獲理學博士學位,同年赴美國北達克他州立大學化學系做博士後研究工作。2005年2月受聘杭州師範大學有機矽化學及材料技術教育部重點實驗室教授,現擔任材料與化學化工學院院長。1994年10月破格晉升副教授,1998年11月破格晉升教授。曾獲山東省科技進步一等獎和二等獎、山東省教育廳理論成果一等獎等多項獎勵。已公開發表學術論文150餘篇,有100多篇被SCI、EI和ISTP收入。主持和參與國家“八五”、“九五”科技攻關計畫、國家自然科學基金、山東省中青年科學家獎勵基金、山東省自然科學基金、浙江省科技計畫重點項目、杭州市科技計畫重點項目等20多項科研課題的研究工作。主要研究方向為高分子化學及高分子化學、有機矽化學和有機矽材料。獲獎情況
1.新型有機矽化合物和聚合物的研究, 山東省自然科學一等獎,1991年2.有機矽微乳液皮革手感劑的研究,山東省科技進步二等獎,2004年
3.新型聚矽烷的研究,獲山東省教育廳科技進步理論成果一等獎,1991年
4.浙江省高等學校特聘教授(錢江學者),2005年
5.浙江省“151”人才第一層次,2006年
6.山東省千名知名技術專家,2003年
發表論文
1. Xu, Z.; Jin, J.; Li, Z.-F.; Qiu, H.-Y.(邱化玉); Jiang, J.-X.; Lai, G.-Q.; Kira, M. Remarkable Substituent Effects on the Activation Energy of Silylene Insertion into Silicon–Chlorine Bonds.Chem. Eur. J. 2009, 15, 8605-8612. (IF:5.454)2. Yang, C.-J.; Chen, X.*; Qiu, H.-Y. * (邱化玉); Zhuang, W.-C.; Chai, Y.-C.; Hao, J.-C. Dissipative particle dynamics simulation of phase behavior of aerosol OT/water system.J. Phys. Chem. B 2006, 110, 21735–21740. (IF:4.189)
3. Wan, J.-H.; Fang, W.-F; Li, Z.-F.; Xiao, X.-Q.; Xu, Z.; Deng; Y., Zhang, L.-H.,;Jiang, J.-X.; Qiu, H.-Y. (邱化玉); Wu, L-B.; Lai, G.-Q.*Novel Ladder π-Conjugated Materials—Sila-Pentathienoacenes: Synthesis, Structure, and Electronic Properties. Chem. Asian J. 2010,5,2290-2296. (IF:4.197)
4. Wan, J.-H.;Mao, L-Y.; Li, Y.-B.; Li, Z.-F.; Qiu, H.-Y. (邱化玉); Wang,C.; Lai, G.-Q.* Self-assembly of novel fluorescent silole derivatives into different supramolecular aggregates: fibre, liquid crystal and monolayer. Soft Matter.2010,6,3195-3201. (IF:4.586)
5. Jin, S.-W, Chen, W.Z*, and Qiu, H.-Y.*(邱化玉) Syntheses and Structural Characterization of a One-Dimensional Chain, Two-Dimensional Noninterpenetrated Grid, and Three-Dimensional Polycatenane Coordination Polymers Assembled from Flexible Bidentate Imidazolyl Ligands. Cryst. Growth Des. 2007,7,2071-2079. (IF:4.04)
6. Lu, C.-X.; Gu, S.-J.; Chen, W.-Z.*; Qiu, H.-Y.*(邱化玉) Platinum(II) complexes with polydentate N-heterocyclic carbenes: synthesis,structural characterization and hydrosilylation catalysis. DaltonTrans. 2010, 39, 4198–4204. (IF:3.58)
7. Lai, G.-Q.; Xu, Z.; Li, Z.-F.; Jiang, J.-X.; Kira, M.*; Qiu, H.-Y. * (邱化玉) Stereoelectronic substituent effects on silylene insertion into the Si-Cl bond. Organometallics 2009, 28, 3591–3593(IF:3.815)
8. Jing, B.; Chen, X.; Zhao, Y.-R; Wang, X.-D.; Cai, J.-G.; Qiu, H.-Y. (邱化玉) Ionic self-assembled organic nanobelts from the hexagonal phase complexes and their cyclodextrin inclusions. J. Phys. Chem. B 2008, 112, 7191-7195. (IF:4.189)
9. Zhang, G.-D; Chen, X.; Zhao, Y.-R; Ma, F.-M.; Jing, B.; Qiu, H.-Y. (邱化玉) Lyotropic liquid-crystalline phases formed by Pluronic P123 in ethylammonium nitrate.J. Phys. Chem. B 2008, 112, 6578-6584. (IF:4.189)
10. Zhang, G.-D.;Chen, X.;Zhao, Y.-R.; Xie, Y.-Z .; Qiu, H.-Y. (邱化玉) Effects of alcohols and counterions on the phase behavior of 1-octyl-3-methylimidazolium chloride aqueous solution. J. Phys. Chem. B 2007, 111,11708-11713. (IF:4.189)
11. Jing, B.; Chen, X.; Wang, X.-D.; Zhao, Y.-R .; Qiu, H.-Y. (邱化玉) Sol-gel-sol transition of gold nanoparticle-based supramolecular hydrogels induced by cyclodextrin inclusion. ChemPhysChem. 2008,9,249-252. (IF:3.636)
12. Peng, J.-J.; Li, J.-Y.; Bai, Y.; Qiu, H.-Y. * (邱化玉); Jiang, K.-Z.; Jiang, J.-X.; Lai, G.-Q.* Ionic liquid (molten salt): Thermoregulated catalyst support for catalytic hydrosilylation process. Catal. Commun. 2008, 9, 2236–2238. (IF:2.791)
13. Zhou, Y.-B.; Zhang, X.-M.; Chen, W.-Z.*; Qiu, H.-Y. * (邱化玉) Synthesis, structural characterization, and luminescence properties of multinuclear silver complexes of pyrazole-functionalized NHC ligands containing Ag-Ag and Ag-pi interactions. J. Organometal. Chem., 2008, 693, 205–215. (IF:1.866)
14. Peng, J.-J.; Li, J.-Y.; Bai, Y.; Gao, W.-H.; Qiu, H.-Y. * (邱化玉); Wu, H.; Deng, Y.; Lai, G.-Q.* Rh(PPh3)3Cl/ionic liquid (molten salt) as a thermoregulated and recyclable catalytic system for hydrosilylation. J. Mol. Catal. A-Chem. 2007, 278, 97–101. (IF:2.814)
15. Li, Z.-F.; Cao, X.-J.; Lai G.-Q.*; Liu, J.-H.; Ni, Y.; Wu, J.-R.; Qiu, H.-Y. * (邱化玉) Controlled introduction of allylic group to chlorosilanes. J. Organometal. Chem. 2006, 691, 4740–4746. (IF:1.866)
16. Li, Z.-F. Yang, C.-J. Zheng, H.-F. Qiu, H.-Y. (邱化玉) ;. Lai, G.-Q* Selective mono- and di-allylation and allenylation of chlorosilanes using indium. J. Organometal. Chem. 2008, 693: 3771-3779.
17. Jiang, K.-Z.; Ni, Y.; Qiu, H.-Y. * (邱化玉); Li, M.-J.; Jiang, J.-X.; Lai, G.-Q.* Separation of the isomers of oligomethylphenylcyclosiloxanes and determination of their structures by capillary GC-MS. Chromatographia. 2006, 64, 689–694. (IF:1.312)
18. Lai, G.-Q.; Peng, J.-J.; Li, J.-Y.; Qiu, H.-Y. (邱化玉); Jiang, J.-X.; Jiang K.-Z.; Shen, Y.-J.* Ionic liquid functionalized silica gel: novel catalyst and fixed solvent. Tetrahedron Lett. 2006, 47, 6951–6953. (IF:2.538)
19. Ju, Y.-D. Xu, L.W.; Li, L.; Lai, G.-Q.*; Qiu, H.-Y. (邱化玉);, Jiang, J.-X.; Lu,Y-X. Noyori’s Ts-DPEN ligand: an efficient bifunctional primary amine-based organocatalyst in enantio-and diastereoselective Michael addition of 1,3-dicarbonyl indane compounds to nitroolefins. Tetrahedron Lett. 2008,49,6773-6777.(Highlighted by SYNFACTS,2008,1328). (IF:2.538)
20. Peng, J.-J.; Li, J.-Y.; Bai, Y.; Gao, W.-H.; Qiu, H.-Y. (邱化玉);,Wu,H.; Deng,Y.; Lai, G.-Q.* Rh(PPh3)3Cl/ionic liquid (molten salt) as a thermoregulated and recyclable catalytic system for hydrosilylation. J. Mol. Catal. A-Chem. 2007, 278, 97-101. (IF:2.814)
21. Xu, L.-W.; Yang, M.-S.; Qiu, H.-Y.* (邱化玉);, Lai, G.-Q.*; Jiang, J.-X. Efficient iron-catalyzed Sakurai-Michael addition of allyltrimethylsilane to chalcones. Synthetic Commun. 2008, 38, 1011-1019. (IF:0.981)
22. Yang, M.-S.; Xu, L.-W.; Qiu, H.-Y.* (邱化玉);, Lai, G.-Q.*; Jian;g, J.-X. Highly efficient indium-catalyzed chemo- selective allylation-etherification and reductive etherification of aromatic aldehydes with functional silanes. Tetrahedron. Lett. 2008, 49, 253-256. (IF:2.538)
23. Yang, M.-S.; Xu, L.-W.; Zhang, F.-B.; Qiu, H.-Y.* (邱化玉); Jiang, J.-X.; Lai, G.-Q.* Highly efficient iron-catalyzed allylation of aromatic aldehydes with allyltriethoxysilane: one-pot and practical synthesis of homoallyl ethers. Appl. Organomet. Chem. 2008, 22,177-180. (IF:1.27)
24. Chen., C.; Qiu, H.-Y.* (邱化玉);Chen, W.-Z.*;Wang, D.-Q. Synthesis, structural characterization, and luminescence properties of multinuclear silver complexes of pyrazole-functionalized NHC ligands containing Ag-Ag and Ag-pi interactions. J. Organometal. Chem., 2008,693, 205- 215. (IF:1.866)
主要科研項目
1.低倍MW級聚光型(CPV)併網電站光伏電池用關鍵材料的研製,國家“863”重點項目(2006AA050203-1),2008.1-2011.122.含Silole和亞矽基σ-π共軛聚合物的設計合成、結構與性能,國家自然科學基金(20974031),2010.1-2010.12
3.含Silole和聯三吡啶Zn(Ⅱ)單元共軛金屬聚合物的設計、合成及性能研究,國家自然科學基金(21074028),2011.1-2013.12
4.有機矽化學若干基礎問題的研究,省高校特聘教授(錢江學者)基金(05TP08),2006.1-2008.12
5.高性能有機矽樹脂綠色合成技術開發研究,省科技計畫重點項目(2007C21G2150010),2007.10-2009.9
6.高性能有機矽材料的研究及產業化,省科技重大專項(2006C11124),2007.6-2009.12
發明專利
1. 一種細旦或超細旦尼龍纖維及其生產方法,ZL200710069547.72. 一種異硫氰酸酯的合成方法,ZL200610048928.2
3. 有機聚矽烷的製備方法,ZL200510061322.8
5. 一種矽氫加成反應擔載型雙金屬催化劑及製備方法,ZL200710068597.3
6. 一種金屬卟啉/二氧化矽降解劑的製備方法,ZL200710067240.3
7. 一種採用新型離子液體聚合引發體系製備高分子化合物的方法,ZL200510061318.1
8. 一種3,4'-二氨基二苯醚的製備及分離提純方法,ZL200610050813.7
9. 超臨界狀態下的原子轉移自由基聚合引發體系,ZL200610172229.9
10.一種反向ATRP引發體系及其在製備高分子化合物的套用,ZL200610048929.7
11. 多官能基矽化合物的製備, ZL200510061321.3
12. 兩步法化學提純甲基苯基二氯矽烷的方法,ZL200510061322.8
13. 一種羥基封端聚甲基苯基矽氧烷的製備方法,ZL200710068595.4
14. 一種側鏈含四硫代富瓦烯結構單元的聚矽烷製備方法,ZL200710070023.X
15. 含稠環基聚矽烷製備方法,ZL200510061319.6