基本信息
原書名:The Physics of Polymers
原出版社:Springer
作者:(德)G.斯特羅伯
叢書名:時代教育.國外高校優秀教材精選
出版社:機械工業出版社
ISBN:9787111376705
出版日期:2012 年4月
開本:16開
頁碼:518
版次:1-1
內容簡介
《高分子物理:“結構與性能”背後的概念(英文版.原書第3版)》對高分子物理的多個領域作了生動而詳細的介紹,內容涵蓋鏈構象,高分子溶液,共混物和嵌段共聚物,半晶態聚合物,聚合物網路,聚合物流體等多種體系。作者還使用了大量的數學處理與實驗結果,對提出的機理與數學模型進行示例與驗證,勾勒出一幅濃墨重彩的高分子物理畫卷。
《高分子物理:“結構與性能”背後的概念(英文版.原書第3版)》可作為化學化工、材料科學和物理學等專業的本科生和研究生教材,也可供有關領域的專家、學者閱讀參考。
目錄
《高分子物理:“結構與性能”背後的概念(英文版.原書第3版)》
出版說明
推薦序
preface(前言)
preface to the first edition/第1版前言
1constitution and architecture of chains/鏈的組成與構造1
2single chain conformations /單鏈構象15
2.1rotational isomeric states /旋轉異構態15
2.2helices/螺旋19
2.3coils /線團22
2.3.1the ideal chain/理想鏈26
2.3.2the expanded chain/膨脹鏈45
2.4the persistent chain/持續鏈55
2.5the ising chain/ 伊辛鏈59
3polymer solutions /聚合物溶液69
3.1dilute and semidilute solutions/稀溶液與半稀溶液70
3.1.1osmotic pressure/滲透壓71
3.2screening of excluded volume forces/排除體積力的禁止82
3.3polyelectrolyte solutions/聚電解質溶液89
3.3.1condensation and screening of charges /電荷的團聚與禁止89
3.3.2chain stretching, salt effects and interchain ordering/鏈伸展、鹽效應與鏈間序95
3.3.3osmotic pressure/滲透壓100
4polymer blends and block copolymers/共混物與嵌段共聚物105
4.1the flory?huggins treatment of polymer mixtures/聚合物混合物的flory?huggins處理方法106
4.1.1phase diagrams: upper and lower miscibility gap/相圖:上臨界與下臨界混溶間隙117
4.2phase separation mechanisms/相分離機理122
4.3critical fluctuations and spinodal decomposition/臨界漲落與旋節線分解129
4.3.1critical scattering/臨界散射132
4.3.2decomposition kinetics/分解動力學143
4.4block copolymer phases/嵌段共聚物的相結構151
4.4.1layered structures/層狀結構155
4.4.2pretransitional phenomena/前轉變現象157
5the semicrystalline state/半結晶態165
5.1structure characteristics/結構特徵167
5.1.1morphological elements /基本形態167
5.1.2structure parameters/結構參數173
5.2kinetics of crystallization and melting/結晶與熔融動力學181
5.3laws for the structure development/結構變化規律190
5.3.1the multistage model/多階段模型199
5.4mechanisms of secondary crystallization/二級結晶機理205
5.4.1the insertion mode/插層模式208
5.4.2surface crystallization and melting/表面結晶與熔融212
5.5crystallization from oriented melts/取向熔體結晶216
6mechanical and dielectric response/力學與介電回響223
6.1response functions/回響函式224
6.1.1viscoelasticity/粘彈性224
6.1.2orientational polarization/取向極化228
6.1.3general relationships/通用公式229
contents6.2relaxatory modes/鬆弛模式236
6.2.1single?time relaxation process/單時間鬆弛過程237
6.2.2retardation and relaxation time spectra/推遲與鬆弛時間242
6.3specific relaxation processes and flow behavior/具體鬆弛過程與流動行為 245
6.3.1local processes/局部過程246
6.3.2glass?rubber transition and melt flow/玻璃?橡膠轉變與熔體流動250
6.3.3the glass transition temperature/玻璃化轉變溫度269
6.3.4relaxation in partially crystalline systems/半晶體系中的鬆弛277
7conjugated polymers/共軛聚合物287
7.1electrooptic activity/光電活性289
7.1.1excitons and free charges/激發與自由電荷289
7.1.2electroluminescence/電發光297
7.2effects of doping/摻雜效應302
7.2.1electrical conductivity/電導率302
7.2.2magnetism and reflectivity/磁性與反射率306
8microscopic dynamics/微觀運動學313
8.1the fluctuation?dissipation theorem/漲落?耗散原理313
8.2the rouse model/rouse模型317
8.2.1stress relaxation/應力鬆弛325
8.2.2the dielectric normal mode /介電基準模式330
8.3entanglement effects in polymer melts/聚合物熔體中的纏結效應333
8.3.1the reptation model/爬行模型338
8.4solution viscosities/溶液粘度 343
8.4.1neutral polymers: hydrodynamic interaction/中性聚合物:流體力學作用344
8.4.2polyelectrolytes: coulomb interaction/聚電解質:靜電作用 352
9non?linear mechanics /非線性力學357
9.1rubber elasticity/橡膠彈性361
9.1.1the fixed junction model of ideal rubbers/理想橡膠的固定結點模型364
9.1.2the cauchy strain tensor/ cauchy應變張量371
9.1.3finger?s constitutive equation/ finger本構方程376
9.2swelling of neutral and electrolytic GELS/中性與電解質凝膠的溶脹384
9.3non?Newtonian melt flow/非牛頓熔體的流動390
9.3.1rheological material functions /流變材料函式391
9.3.2the lodge liquid/ lodge液體398
9.3.3the stress?optical rule/應力?光學規則404
10deformation, yielding and fracture/形變、屈服與斷裂415
10.1shear deformation in semicrystalline polymers/半晶聚合物中的剪下形變418
10.1.1critical strains/臨界應變418
10.1.2constituents of the drawing stress/拉伸應力的成分426
10.1.3the mechanics of neck formation/細頸形成機理429
10.1.4fibrillar state of order/纖維化有序態435
10.2crazing/銀紋 444
10.3brittle fracture/脆性斷裂450
10.3.1linear fracture mechanics /線性斷裂力學453
10.3.2the slow mode of crack growth/裂縫生長的緩慢模式455
ascattering experiments/散射實驗463
a.1fundamentals/基本概念463
a.1.1basic equations/基本方程464
a.1.2time?resolved scattering experiments/時間分解的散射實驗468
a.2absolute intensities/絕對強度471
a.3low angle scattering properties/小角散射性質474
a.3.1guinier?s law/ guinier公式474
a.3.2forward scattering/前散射476
a.4special polymer systems/特種聚合物體系477
a.4.1binary mixtures and block copolymers/二元混合物與嵌段共聚物477
a.4.2two?phase layer systems/兩相層狀體系484
bglossary of symbols/術語與符號493
cbibliography/參考書目501
references/參考文獻505
index/索引