人物簡介
由萬勝,男,1963年生,理學博士學位。遼寧師範大學化學化工學院教授(2002-),碩士生導師(2002-)。東北師範大學兼職教授,博士生導師(2006-)。中科院大連化學物理研究所503組流動工作人員。學習經歷
1997.09 - 2000.12 東北師範大學化學系學習 獲理學博士學位 專業為無機化學, 研究方向為多金屬氧酸鹽化學,導師:王恩波教授1984.09 - 1987.07 東北師範大學化學系學習 獲理學碩士學位 專業為無機化學,研究方向為多金屬氧酸鹽化學,導師:王恩波教授1980.09 - 1984.07 東北師範大學化學系學習 獲理學學士學位。工作經歷
2004.11 - 2005.04 法國 Paul Pascal研究所高訪。2001.04 - 2004.12 中科院大連化學物理研究所催基礎國家實驗室在職博士後。
研究課題為太陽能光催化分解水制氫 ,合作導師:李燦院士。
2001年12月日本東京工業大學短期訪問。
1987.07 - 至 今 遼寧師範大學化學系工作。講授過無機化學、配位化學、有機化學實驗、高等無機化學、多酸化學等 。 曾擔任:化學系實驗管理室主任、系主任助理、系副主任、化學化工學院副院長和功能材料化學研究所副所長。 1995年評為副教授;2002年評為教授;碩士生導師;2006年被聘為東北師範大學博士生導師。
承擔的科研項目
1.2009.01-2013.12 參加國家973項目“高效低成本直接太陽能化學及生物轉化與利用的基礎研究”的研究工作。 項目編號:2009CB2200002.2008.1-2008.12 主持國家自然科學基金項目,多金屬氧酸鹽光電化學分解水制氫的基礎研究,8萬元。批准號:20773057
3.2006.1-2007.12 主持遼寧省教育廳基礎研究項目,新型多金屬氧酸鹽合成及光電化學分解水制氫的研究,3萬元。編號為:605L207
4.2003.12-2005.12 主持遼寧省博士後啟動基金,多金屬鈮、鉭氧酸鹽水熱合成及其光催化分解水制氫的研究,4萬元。 批准號:20031059
5.2003.12-2005.12 主持大連市科委優秀人才基金,多金屬鈦氧酸鹽水熱合成及其光催化分解水制氫的研究,5萬元。
6.2003.01-2005.12 主持國家自然科學基金項目、鋯和鉭氧化物的摻雜及光催化分解水制氫的研究,22萬元。批准號:20273070。
7.2003.12-2008.11 國家973計畫項目、用太陽能規模製氫的基礎研究子課題相連續制氫的微觀機理、結構與性能的測量和表征主持 人。440萬元。編號為:2003CB214504。
發表論文及專利
1. Lan-Cui Zhang, Shu-Li Zheng, Han Xue, Zai-Ming Zhu, Wan-Sheng You, Yang-Guang Li* and Enbo Wang*. New tetra(organotin)-decorated boat-like polyoxometalate, Dalton. Trans.2010, 39, 3369.2. Li-Mei Dai, Wan-Sheng You*, Yang-Guang Li , En-Bo Wang, Li-Jun Qi, Jing Tang, Xiu-Li Bai, A new pure Mo-oxide-based organic-inorganic hybrid framework templated by vanadium-substituted Keggin anions, Inorg. Chem. Commun. 2010, 13, 421–424.
3. Fang Yong, You Wansheng*, Guo Xin, Zhu Zaiming, Dai Limei and Zhao Yi, Two new 1D coordination polymers constructed from {M(H2O)(dpa)} subunits bridged through [MoO4] anions (M = copper, cobalt and dpa = 2,2- dipyridylamine), 結構化學, 2009, 28,1553-1560.
4. Xuemei Han, Wansheng You*, Limei Dai, Lijun Qi, Yong Fang and Weiwei Li. Two New 2D and 1D Ni(II) Coordination Polymers Bridged by Vanadium-Substituted Keggin Polyoxotungstophosphates: Hydrothermal Synthesis and Crystal Structure,J. Clust. Sci.2009, 20, 707-716.
5. Wei-wei Li, Qi Wang, Wan-sheng You*, Lijun Qi, Li-mei Dai and Yang Fang. Hydrothermal Synthesis, Crystal Structure and Electrochemical Behavior of Two New Isomorphic Layered Vanadates,Inorg. Chem. Commun. 2009, 12, 1185-1188.
6. Limei Dai, Wansheng You*, Enbo Wang, Xiaolan Wang, Xuemei Han, Weiwei Li and Yong Fang, 2D rhombus-grid networks constructed from vanadium-substituted Keggin-type polyoxomolybdophosphates and Cd/Zn complex fragments, Inorg. Chim. Acta.2009, 362, 4967-4971.
7. Li-Mei Dai, Wan-Sheng You*, Yang-Guang Li, En-Bo Wang* and Cui-Ying Huang, A new polyoxometalate-templated Mo/V-oxide-based organic–inorganic hybrid framework with honeycomb-like nanochannels, Chem. Commun.2009, (19), 2721 – 2723.
8. Limei Dai, Wansheng You*, Enbo Wang*, Shuixing Wu, Zhongmin Su*, Qinghua Du, Yi Zhao and Yong Fang, Two Novel One-Dimensional α-Keggin-Based Coordination Polymers with Argentophilic {Ag3}/{Ag4} Clusters, Cryst. Growth. Des.2009, 9 (5), 2110-2116
9. Qinghua Du, Dawei Song, Wansheng You*, Yi Zhao, Tingting Gan, and Limei Dai,Synthesis, Crystal Structure and Electrochemical Properties of a New Adduct of Benzo-15-crown-5 and H3PMo12O40,Z. Naturforsch.2009, 64b, 274 – 280.
10.Yi Zhao, Wansheng You*, Limei Dai, Lancui Zhang, Dawei Song and Qinghua Du,Hydrothermal synthesis, crystal Structure and electrochemical property of a new 1D ribbon-like coordination polymer based on octamolybdate anions,Z. Anorg. Allg. Chem.2008, 634, 2639-2642
11.Tianhui Hu, Wansheng You*, Limei Dai, Yi Zhao, Yong Fang, and Xuefang Zheng,Influence of Hydrogen Bonding Interactions on the Conformation of Ribbon-like Zn(II) Complexes Bridged by Molybdates,Z. Naturforsch.2008, 63b, 1262-1266.
12.Dawei Song, Wansheng You*,Yi Zhao, Tianhui Hu, Qihua Du, Xuefang Zheng, Syntheses, Crystal Structures and Electrochemical Properties of Two New Supramolecular Compounds Based on Hexamolybdates and Crown Ethers, J. Mol. Struct.2008, 888, 337-343.
13.Xiao-Li Yu; Wan-Sheng You*; Xin Zhang; Xin Guo; Lan-Cui Zhang; Yan Xu; Zhen-Gang Sun, Hydrothermal syntheses and crystal structures of two transition metal complexes supported by vanadate {V4O12}: {[M(dpa)2]2V4O12} (M = Co, Ni. dpa = 2,2'-dipyridylamine), J. Coord. Chem.2008, 61(9), 1475-1483.
14.Tian-hui Hu, Qi Wang, Wan-sheng You*, Da-wei Song, Cui-ying Huang, Yan Xu, Zhen-gang Sun. Two New Layered Complexes Supported by Helical {VO3}n Chains: Hydrothermal Syntheses and Crystal Structures of [M(dpa)V2O6] (M = Zn(II) and Cu(II); dpa=2,2'-dipyridylamine), Inorg. Chem. Commun.2008, 11, 470-474
15.Ying-Ya Liu, Jian Zhang, Li-Xian Sun*, Fen Xu*, Wan-Sheng You, Yi Zhao,Solvothermal synthesis and characterization of a lithium coordination polymer possessing a highly stable 3D network structure,Inorg. Chem. Commun.2008, 11, 396-399.
16.Qi Wang, Xiao-li Yu, Wan-sheng You*, Yi Zhao, Cui-Ying Huang, Zhen-gang Sun,Two Novel Isomeric Complexes Supported by Vanadates {V4O12}: [{Cu(dpa)2}2V4O12] (dpa = 2, 2'-dipyridylamine),Inorg. Chem. Commun.2007, 10, 1465-1468.
17.Xiao-li Yu, Wan-sheng You*, Xin Guo, Lan-cui Zhang, Yan Xu, Zhen-gang Sun and Rodolphe Cléac,Magnetic properties and structure of a new one-dimensional azido-bridged nickel(II) coordination polymer, Inorg. Chem. Commun. 2007, 10, 1335-1338.
18.Guang-Ning Zhang, Yong Fang, Cui-Ying Huang and Wan-Sheng You*, Dichloridobis{2-[(triphenylmethyl)amino]pyridine-k-N}zinc(II),Acta.Cryst. E. 63(8), m2247.
19.ZHANG Xin, YOU Wan-sheng*, ZHU Zai-ming, DANG Li-qin, SUN Zhen-gang and ZHENG Xue-fang,Syntheses, Crystal Structures and Characterization of Two Zeotype Crystals of K4[Cr3O(H2O)3(OOCH)6]2[P2W18O62]·9.5H2O and K4[Cr3O(H2O)3(OOCH)6][H3P2W17Co(H2O)O61]·20H2O, Chem. Res. Chinese. U.2007, 23 (1),:8-13.
20.Xiao-Li Yu, Yong Fang, Cui-Ying Huang, Yuan-Peng Gu and Wan-Sheng You*, Bis(dicyanamido- k-N)(di-2-pyridylamine- k-N,N')zinc(II), Acta.Cryst.2007, E63, m358-m359.
21.Wan-sheng You*, Xin Guo, Xiao-li Yu, Cui-ying Huang, Lan-cui Zhang and Zhen-gang Sun, A novel 1D molybdenum oxide ribbon bridged by pyridine-4-carboxylic ligands: [(C6H4NO2)Mo2O5OH],Inorg. Chem. Commun. 2007, 10(1), 23-26.
22.Yan Xu, Lin-Bo Nie, Dunru Zhu, You Song, Guang-Peng Zhou, and Wan-Sheng You, Two New Three-Dimensional Porous Polyoxometalates with Typical ACO Topological Open Frameworks: [Cu4V13V5O42(NO3)(C3H10N2)8]·10H2O}n and {[Cu4V12V6O42(SO4)(C3H10N2)8]·10H2O}, Cryst. Growth. Des. 2007,7, 925-929.
23.LEI MENG, ZHENGANG SUN*, DAPENG DONG, HUI CHEN, YANYU ZHU, JING ZHANG, YAN ZHAO and WANSHENG YOU, Hydrothermal synthesis and crystal structures of two new divalent metal phosphonates with layered structure,J. Coord. Chem.2007, 60(19), 2075-2083.
24.LIANYI CUI, ZHENGANG SUN, HUI CHEN, LEI MENG, DAPENG DONG, CUIHUA TIAN, ZAIMING ZHU andWANSHENG YOU, Hydrothermal syntheses, crystal structures, and thermal stability of two new 3D open-framework metal(II) phosphonates, J. Coord. Chem.2007, 60(12), 1247-1254.
25.Zhen-Gang Sun; Da-Peng Dong; Jing Li; Lian-Yi Cui; Yan-Yu Zhu; Jing Zhang; Yan Zhao; Wan-Sheng You; Zai-Ming Zhu, Hydrothermal synthesis, crystal structure and thermal stability of a new 2D layered metal(II) phosphonate: [NH3CH2CH2NH3][Fe2(O3PCH(OH)CO2)2(H2O)2]·2H2O, J. Coord. Chem. 2007, 60(23), 2541-2547.
26.CUI-HUA TIAN, ZHEN-GANG SUN*, LAN-CUI ZHANG, HAI-DONG LIANG, ZAI-MING ZHU, WAN-SHENG YOUand YUAN-PENG GU, Synthesis and characterization of two new b-octamolybdate complexes [NH4][Y(DMF)5(H2O)3][Mo8O26]·CH3CN and [NH4][Ce(DMF)7Mo8O26], J. Coord. Chem.2007, 60,(7-9), 985-993.
27.Cui-hua Tian, Zhen-gang Sun*, Jing Li, Xue-fang Zheng, Hai-dong Liang, Lan-cui Zhang, Wan-sheng You, Zai-ming Zhu, Synthesis and crystal structures of two new inorganic-organic hybrid polyoxomolybdate complexes: [Himi]4[{Co(imi)2(H2O)2}Mo7O24]·4H2O, and [Zn(imi)4]2[(imi)2Mo8O26]·6H2O,Inorg. Chem. Commun.2007, 10, 757-761.
28.Zhen-Gang Sun, Hui Chen, Zhong-Min Liu, Lian-Yi Cui, Yan-Yu Zhu, Yan Zhao, Jing Zhang, Wan-Sheng You, Zai-Ming Zhu, Synthesis, characterizations, and crystal structure of a novel 2D metal phosphonate: Na2[Cd2(H2O)3(O3PCH(OH)CO2)2]·2H2O, Inorg. Chem. Commun. 2007, 10,283-286.
29.Jing Li, Lei Meng, Zhen-Gang Sun*, Lian-Yi Cui, Jing Zhang, Yan-Yu Zhu, Da-Peng Dong, Hui Chen, Wan-Sheng You, Zai-Ming Zhu, Synthesis and characterizations of a layered antimony (III) phosphonate: [NH2CH2CH2NH2][Sb2(O3PCH(OH)CO2)2], Inorg. Chem. Commun.2007, 10, 535-537.
30.Lian-yi Cui, Zhen-gang Sun, Zhong-min Liu, Wan-sheng You, Zai-ming Zhu, Lei Meng, Hui Chen, Da-peng Dong, Synthesis and crystal structure of Zn[O3PCH(NH2)CH3] 2H2O, the first zinc a-aminoethylphosphonate with a layer structure,Inorg. Chem. Commun. 2006, 9, 1232-1234.
31.Zhen-Gang Sun, Lian-Yi Cui, Zhong-Min Liu, Da-Peng Dong, Lei Meng, Hui Chen, Lan-Cui Zhang, Zai-Ming Zhu, Wan-Sheng You, Hydrothermal synthesis and crystal structure of a novel lead(II) phosphonate containing trifunctional phosphonate anions: Pb4O[O3PCH2-NC4H7-CO2]2,Inorg. Chem. Commun.2006, 9, 1121-1124.
32.ZHEN-GANG SUN, LAN-CUI ZHANG, ZHONG-MIN LIU, LIAN-YI CUI, CUI-HUA TIAN, HAI-DONG LIANG, ZAI-MING ZHU and WAN-SHENG YOU, Synthesis, spectroscopic properties and crystal structure of organophosphoryl polyoxotungstate a-[Bu4N]3H[PhCH2P(O)]2SiW11O39, J. Coord. Chem. 2006, 59, 1557-1564.
33.Yong Fang, Cui-Ying Huang, Zai-Ming Zhu, Xiao-Li Yu and Wan-Sheng You*,Dichlorobis{2-[(triphenylmethyl)amino]pyridyl} cobalt(II),Acta. Cryst.2006. E62, m3347-m3348.
34.Zhibin Lei, Yi Xiao, Liqin Dang, Min Lu, Wansheng You,Fabrication of ultra-large mesoporous carbon with tunable pore size by monodisperse silica particles derived from seed growth process, Micropor. Mesopor. Mat.2006, 96, 127-134.
35.Cuiying Huang, Yong Fang, Yuanpeng Gu, Lancui. Zhang and Wansheng You*,Bis(dicyanamidato-k-N)(di-2-pyridylamine-k-N,N')nickel(II),Acta. Cryst. 2006,E 62(11), m3068---m3070.
36.Zhen-Gang Sun, Lian-Yi Cui, Zhong-Min Liu, Lei Meng, Hui Chen, Da-Peng Dong, Lan-Cui Zhang, Xai-Ming Zhu, Wan-Sheng You, Hydrothermal synthesis, crystal structures and characterizations of a novel 3D metal phosphonate: Mg0.5Cd[O3PCH(OH)CO2], Inorg. Chem.Commun.2006,9(10) 999-1001.
37.Zheng-Bo Han, Yi Ma , Zhen-Gang Sun, Wan-Sheng You,Hydrothermal synthesis, crystal structure and photoluminescent properties of a novel 3-D coordinationpolymer [Cd2(pydc)2(H2O)]n (pydc = pyridine-2,3-dicarboxylate),Inorg. Chem. Commun. 2006, 9, 844-847
38.Yan Xu, Liying Cheng, Wansheng You, Hydrothermal Synthesis and Structural Characterizations of Two New Germanates with a Novel Topological Framework and Unusual Ge4(OH)4 Cubane,Inorg. Chem. 2006, 45, 7705-7708.
39.Liqin Dang, Wansheng You* ,Xin Zhang, Cuiying Huang, Zhibin Lei, Zhengang Sun, Can Li*,Photocatalytic hydrogen evolution of Keggin-type polyoxotungstates and their electrochemical behaviors,Chinese. Chem. Lett.2006, 17(7), 973-976.
40.Xin Zhang, Wan-sheng You*, Zai-ming Zhu, Li-qin Dang, Zhen-gang Sun and Xue-fang Zheng,Hydrothermal synthesis and characterization of a novel crystal containing [Co4O4] cubane core: [Co4O4(dpaH)4(CH3COO)2]2V4O12·5H2O, Inorg. Chem. Commun. 2006,9(5) 526-528.
41.Cuiying HUANG, Wansheng YOU*, Liqin DANG, Zhibin LEI, Zhengang SUN and Lancui ZHANG, Effect of NdDoping on Photocatalytic Activity of TiO2 Nanoparticles for Water Decomposition to Hydrogen,Chinese. J. Catal. 27(3), 203-209.
42.黃翠英、由萬勝*、黨利琴、雷志斌、孫振剛、張蘭翠,釹摻雜對納米TiO2光催化分解水制氫活性的影響,催化學報,2006,27(3), 203-209.
43.Zhibin Lei, Guijun Ma,Meiying Liu, Wansheng You, Hongjian Yan, Guopeng Wu, T. Takata, M. Hara, K. Domen, Can Li, Sulfur-substituted and zinc-doped In(OH)3 A new class of catalyst for photocatalytic H2 production from water under visible light illumination, J. Catal. 2006, 237, 322-329.
44.劉美英, 由萬勝, 雷志斌, 宗 旭, 應品良, 李 燦,肼溶膠-凝膠法製備高比表面積納米氮化鈦粉體的研究,高等學校化學學報,2006,27(8),1488-1491。
45.劉美英、由萬勝、雷志斌、高田岡、堂免一成、李燦,可見光作用下LaTaON2催化劑光催化分解水制氫,催化學報,2006,27(7),556-558。
46.Zhu Jing,You Wansheng*, Zhu Zaiming, Sun Zhengang, Zhang Lancui, Gu Yuanpeng, 12-tungstophosphates Immobilized on Chemically Modified Mesoporous Silica SBA-15, Chem. Res. Chinese. U.2005, 21(3), 264-267.
47.朱再名,由萬勝*,孫振剛,包東梅, 魏永革,谷源鵬,張蘭翠,K3[Cr3O(OOCH)6(H2O)3][α-GeW12O40]·7H2O的合成、結構及特性研究,分子科學學報,2005,21(1),47-53。
48.Sun Zhengang, Zhu Zaiming,You Wansheng, Zheng Xuefang and Gu Yuanpeng Synthesis and Spectroscopic Characterization of Organothiophosphoryl Polyoxotungstates α-[RP(S)]2PW9O34(R = C6H5, C6H11), Chinese. J. Chem.2005,23, 530-532.
49.Meiying Liu, Wansheng You, Zhibin Lei, Guohua Zhou, Jianjun Yang, GuopengWu, Guijun Ma, Guoyou Luan, Tuyoshi Takata, Michikazu Hara, Kazunari Domen, and Can Li, Water reduction and oxidation on Pt-Ru/Y2Ta2O5N2 catalyst under visible light irradiation, Chem. Commun. 2004, 2192-2193.
50.Sun Zhen-gang, You Wan-sheng, Zhu Zai-ming, Gu Yuan-peng and Liu Jing-fu, Synthesis and Spectroscopic Characterization of organothiophosphoryl polyoxometalates α-[C6H11P(S)2]XW11O39 (X=P, Si, Ge, Ga), Chem. Res. Chinese. U. 2004, 20(5),517-520.
51.Zhibin Lei, Wansheng You, Meiying Liu, Guohua Zhou, T. Takata, M. Hara, K. Domen, Can Li, Photocatalytic water reduction under visible light on a novel ZnIn2S4 catalyst synthesized by hydrothermal method, Chem. Commun. 2003, 2142-2143.
52.Zheng-Gang Sun, Wan-Sheng You, Jing Li and Jing-Fu Liu, Synthesis and spectroscopic characterization of organophosphoryl tungstosilicates α-[RP(O)]2SiW11O39, Inorg. Chem. Commun. 2003, 6, 238-240.
53.Zongxuan Jiang, Yan Liu, Xiuping Sun, Fuxia Sun, Changhai Liang, Wansheng You, Chongren Han and Can Li, Activated Carbons Chemically Modified by Concentrated H2SO4 for the Adsorption of the Pollutants from Wastewater and the Dibenzothiophene from Fuel Oils, Liangmuir, 2003, 19, 731-739.
54.Wansheng You, Enbo Wang, Lin Xu, Zaiming Zhu, Yuanpeng Gu, A molecule based in polyoxometalate acid and crown: synthesis and structure of [(H3O)(C20H24O6)]2[HPMo12O40]·C20H24O6·3MeCN·H2O (C20H24O6=dibenzo-18-crown-6), J. Mol. Struct.2002, 605(1),41-49.
55.Wansheng You, Enbo Wang, Yan Xu, Yangguang Li, Lin Xu and Changwen Hu,An alkali metal-crown ether complex supported by a Keggin anion through the three terminal oxygen atoms in a single M3O13 triplet: synthesis and characterization of [{Na(dibenzo-18-crown-6)(MeCN)}3{PMo12O40}],Inorg. Chem.2001, 40(21), 5468-5471.
56.Zhengbo Han, Enbo Wang, Wansheng You, Shuxia Liu, Changwen Hu, Synthesis and crystal structure of a novel compound: [H3PMo12O40][CO(NH2)2]3·H2O, J. Mol. Struct.2001, 595(1-3), 7-13.
57.Wan-Sheng You, En-Bo Wang, Lin Xu, Chang-Wen Hu and Guo-You Luan, Chains of (4,4'-bipyridyl)copper(Ⅰ) bridged by dimolybdate units, Acta. Cryst.2000, C56, 289-290.
58.Wansheng You, Enbo Wang, Qinglin He, Lin Xu, Yan Xing, Hengqing Jia, Synthesis and crystal structure of a new supermolecular compound: [C12H24O6][H3PMo12O40]·22H2O (C12H24O6=18-crown-6), J. Mol. Struct. 2000, 524(1-3), 133-139.
59.Wansheng You, Enbo Wang, Hong Zhang, Lin Xu, Yibo Wang, Synthesis and structural Characterization of a new supermolecular compound: H3PW12O40·6C14H20O5·16H2O (C14H20O5=benzo-15-crown-5), J. Mol. Struct.2000, 554,141-147.
60.Wansheng You, Zaiming Zhu, Enbo Wang* Lin Xu and Changwen Hu, Synthesis and X-ray structure of [(H3O)(C14H20O5)2][Me2NH2]2 [PMo12O40]·2C14H20O5 (C14H20O5 = benzo-15-crown-5; Me2NH = dimethylamine), J. Chem. Crystallogr. 2000, 30(9): 577-581.
61.Guo-You Luan, En-Bo Wang, Wan-Sheng You, Lin Xu and Qing-Lin He, A Hydrated ethylenediammonium salt of a new polymeric polyoxoanion (H2en)4[Co(H2O)2(OH)2(VO)6(HPO4)4(PO4)4]·3H2O, Acta. Cryst.2000, C56, e284-e285.
62.由萬勝,王軼博,王恩波,許林, 胡長文,室溫固相反應製備Keggin結構雜多酸銨鹽納米粒子,高等學校化學學報,2000,21(11),1636-1638.
63.由萬勝,王軼博,王恩波,欒國有,韓正波,α-Keggin型(NH4)4HPW10V2O40·2.5H2O水熱合成及結構特徵研究,分子科學學報,2000,16(2),77-81.