人物簡介
2001.11-2003.12月分別在英國皇家學會和德國巴斯夫公司的資助下師從國際著名金屬有機化學家M.F.Lappert教授、英國皇家院士進行了為期兩年的博士後研究工作學進行合作研究。近五年來在OrganOMEtallics、Dalton Transactions、Journal of Materials Chemistry 等雜誌上發表論文60餘篇,已申請中國發明專利7項,授權4項。
研究興趣
有機化學;金屬有機化學;精細化學品化學;綠色化學
or ButCN and PhCN”, J. Organomet. Chem., 2004, 689, 1342-1349.
發表論文
1. “The First Heterotrimetallic Salts: Synthesis, Structures andSuperBaseReactivity of the Crystalline tert-Butoxides [Li4Na2K2(OtBu)8(m-L)]n [L = h6: h6-C6H6 (1), N,N’-TMEDA) (2)]”, Angew. Chem. Int. Ed. 2008, in press.
2. “Syntheses, structures and reactions of a series of β-ketiminatoyttriumcompounds”, Dalton Trans., 2008, 1073-1080.
3. “Synthesis, characterization of a novel zinc diamine-bisphenolate complex and its application as an initiator for ring-opening polymerization of rac –lactide” Inorg. Chem. Commun., 2008, in press.
4. “Synthesis and structures of some sterically hindered zinc complexes containing 6-membered ZnNCCCN and ZnOCCCN rings”, J. Organomet. Chem., 2008, in press.
5. “Synthesis, structure and catalytic properties of a novel zirconium guanidinato complex [Zr{ArNC(NMe2)N(SiMe3)}(m2- Cl)Cl2]2 [ Ar = 2,6- iPr2- C6H3]”, J. Organomet. Chem., 2007,692, 5195-5202.
6. Synthesis and structures of some heterometallic [(Li, Y)2, (M3, Ce) (M= Lior Na), (Li, Zr2) and (Li, Zr)4] oligomeric diamides derived from 1,2-bis(neopentylamino)benzene”, Dalton Trans., 2006, 2991–2997.
7. “Synthesis and structures of some bimetallic (Li/Ca, Li/Zn, Li/Li) diamidesderived from 1,2-bis(neopentylamino)benzene and ofLi2[{N(SiMe2NPri2)}2C6H4-1,2](thf)3” , Dalton Trans., 2006, 1181–1187.
8. “b-Diketiminates of Some Main Group Elements: New Structural Motifs”, Modern Aspects of Main Group Chemistry, 2005, 192-207, Publisher: American Chemical Society, Washington, DC.
9. “Synthesis and structures of the chelating diamido zirconium andhafniumcompounds”, Appl. Organomet. Chem., 2005, 19, 1010-1014.
10. “b-diketiminates of some main group elements: New structural motifs”, ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 227: U1433 Part 1 2004, Publisher: AMER CHEMICAL SOC, WASHINGTON, ISSN: 0065-7727.
11. “Lanthanide metal amides revisited; the use of the 2,2,6,6-tetramethylpiperidinato (TMP) ligand”, J. Mater. Chem., 2004, 14, 3266 - 3273.
12. “Synthetic and structural experiments on yttrium, cerium and magnesium trimethylsilylmethyls and their reaction products with nitriles; with a note on two cerium b-diketiminates”, Dalton Trans., 2004, 1567-1577.
13. “Synthesis and structures of four crystalline lithium b-diketiminates derived from [Li{CH(SiMe3)(SiMe2OMe)}]8 and PhCN or ButCN and PhCN”, J. Organomet. Chem., 2004, 689, 1342-1349.
14. “Syntheses and Structures of Alkali Metal Silylmethyls and Derived Azaallyls and b-Diketiminates”, ALKCHEM-3, Third International Conference on the Chemistry of the Alkali and Alkaline Earth Metals, P. 60, 28. 09-02.10. 2003, Würzburg, Germany.
15. “Some Unusual Alkai Metal or Magnesium Silyl-substituted Complexes: Steric and Electronic Effects and Rearrangements”, ALKCHEM-3, Third International Conference on the Chemistry of the Alkali and Alkaline Earth Metals, P. 27, 28. 09-02.10. 2003, Würzburg, Germany.
16. “Synthesis and structures of crystalline lithium 1-azaallyls and a 1,3-diazaallyl derived from Li{CH(SiMe3)(SiMe3-n(OMe)n)} (n = 1 or 2) and Li{CH(SiMe2OMe)2} andrcn(R = But, Ph, 2,5-Me2C6H3, or Ad)”, J. Organomet. Chem., 2003, 683, 83-91
17. “Synthesis and Structures of Crystalline Li, Na, K, and Mg Silylmethyls Derived from the Ligands [CH(SiMe3){ SiMe3-n(OMe)n}]- (n = 1 or 2), [CH(SiMe2OMe)2]-, and [CH(SiMe3)(SiMe2Ph)]-”, Organometallics, 2003, 23, 2505-2516.
18. “STUDIES IN 1-AZAALLYLMETAL CHEMISTRY”, Allyl Symposium, ACS Meeting, 18 –19th August 2002, Boston, USA.
19. “SYNTHESIS, STRUCTURES AND REACTIONS OF METAL COMPOUNDS OF A NOVEL b-DIKETIMINATO LIGAND”, 20th International Conference on Organometallic Chemistry, Corfu, Greece July, 2002.
20. “STUDIES IN 1-AZAALLYLMETAL CHEMISTRY”, Allyl Symposium, ACS Meeting, 18 –19th August 2002, Boston, USA.
21. “Synthesis and structures of novel chiral lithium amidinates and mono-and di-lithium(1R,2R)-(-)-1,2-(NHSiMe3)2C6H10”, J. Chem. Soc., Dalton Trans., 2002, 1401-1405.
22. “Addition reactions of bis(trimethylsilyl)methyl- and 1-azzallyl-lithium with cyanoamines into triazines or b-diketiminatolithium compounds”, J. Organomet. Chem., 2002, 655, 89-95.