內容簡介
本書編寫是為了適應物理化學雙語教學這一全新的教學模式，解決物理化學雙語教材短缺的問題。在編寫的過程中儘量做到內容精練、簡明易懂，並對每一部分重點內容均採用英、漢雙語進行編寫。本書共分十章，內容包括：氣體的pVT性質；熱力學第一定律；熱力學第二定律；多組分系統熱力學；化學平衡；相平衡；電解質溶液；電化學；界面現象；化學動力學。
本書既可作為高等院校雙語物理化學教學的教材使用，也可以作為非雙語物理化學教學的參考教材。
目錄
Introduction
0.1 Physical chemistry
0.1.1 Contents of physical chemistry
0.1.2 Issues to be solved by physical chemistry
0.1.3 Advice for studying physical chemistry
0.2 Indication and operation of physical quantity
0.2.1 Indication of physical quantity
0.2.2 Operation of physical quantity
Chapter 1 The pVT properties of gases
1.1 State equation of the perfect gas
1.1.1 Empirical law of gas
1.1.2 State equation of the perfect gas
1.1.3 Model of the perfect gas
1.2 Mixture of the perfect gas
1.2.1 Composition of perfect gas mixture
1.2.2 Dalton’S law of partial pressures
1.2.3 Amagat’S law of partial volumes
1.2.4 Meanmolarmass of mixed gas
1.3 Liquefaction of real gas and critical properties
1.3.1 Saturated vapor pressure of liquid
1.3.2 Liquefaction of real gas and critical properties
1.4 State equations of real gas
1.4.1 The van der Waals equation
1.4.2 The virial equation of state
1.5 The law of corresponding states
1.5.1 Compression factors
1.5.2 The law of corresponding states。
EXERCISES
Chapter 2 The first law of thermodynamics’
2.1 The basic concept of thermodynamics
2.1.1 System and surroundings
2.1.2 Extensive property and intensive property of system
2.1.3 State and state function of system
2.1.4 Equilibrium state of thermodynamics
2.1.5 Process and path
2.2 The first law of thermodynamics
2.2.1 Heat
2.2.2 Work
2.2.3calculationof volume work
2.2.4 Thermodynamic energy
2.2.5 The first law of thermodynamics.
2.3 The heat at constant volume.the heat at constant pressure and enthalpy
2.3.1 The heat at constant volume
2.3.2 The heat at constant pressure
2.3.3 Enthalpy.
2.3.4 Hess’s Law
2.4 Heat capacity
2.4.1 Heat capacity
2.4.2 Relation between Cp,mand P
2.4.3 Empirical formula between Cp,m and T
2.4.4 Relation between Cp,m and Cv,m
2.4.5jouleexperiment
2.5 Reversible process and equation of adiabatic reversible process of the perfect gas
2.5.1 Reversible process
2.5.2 Isothermal reversible process of the perfect gas.
2.5.3 Adiabatic reversible process of the perfect gas
2.6 Phase transformation process.
2.6.1 Phase and enthalpy of phase transition.
2.6.2 Calculation of AH of phase transformation process
2.7 Standard molar enthalpy of reaction
2.7.1 Chemical stoichiometric number
2.7.2 Extent of a reaction
2.7.3 Molar enthalpy of reaction
2.7.4 Standard molar enthalpy of reaction
2.8 Standard molar enthalpy of formation and standard molar enthalpy of combustion
2.8.1 Standard molar enthalpy of formation
2.8.2 Standard molar enthalpy of combustion
2.8.3 The temperature—dependenceof A，n(T)一Kirchhoff’S formula.
2.8.4 The relation between Qp and Qv.
2.8.5 Maximum temperature of explosion and flame reaction
2.9 Throttling process and Joule—Thomson effect
2.9.1 Joule—Thomson experiment
Chapter3 The Second Law of thermodynamics
Chapter4 The thermodynamics of multi-component systems
Chapter5 Chemical equilibrium
Chapter6 Phase equilibrium
Chapter7 Electrolyte solution
Chatper8 Electrochemical system
Chapter9 Interface phenomena
Chapter10 Chemical Kinetics
REFERENCE BOOKS
