圖書信息
出版社: 世界圖書出版公司; 第1版 (2004年1月1日)
外文書名: Vogel's Textbook of Practical Chemistry 5th ed. Vo1.1
平裝: 823頁
正文語種: 英語
開本: 24
ISBN: 7506265842
條形碼: 9787506265843
尺寸: 22 x 14.6 x 4 cm
重量: 975 g
內容簡介
《沃氏實用有機化學教程(第1卷)(第5版)》內容簡介：This is the second time that we have prepared a new edition of Vogel's Textbook of Organic Chemistry and it is important to reaffirm the aims set out by the late Dr A. I. Vogel in the preface to the first edition. Thus in this new edition every endeavour is made to retain the comprehensive character of the book, and to ensure that it continues to be a one-volume reference text which is of value to practising organic chemists throughout their undergraduate, postgraduate and subsequent careers.
目錄
CHAPTER 1 ORGANIC SYNTHESIS
1.1 INTRODUCTION
1.2 STRUCTURE OF THE TARGET MOLECULE
1.3 REACTION MECHANISM AND THE METHODOLOGY OF SYNTHESIS
1.4 REACTION MECHANISM AND THE STRATEGY OF SYNTHESIS
1.5 CONCLUSION
REFERENCES
CHAPTER 2 EXPERIMENTAL TECHNIOUES
2.1 GENERAL INSTRUCTIONS FOR SAFE WORKING IN ORGANIC CHEMICAL LABORATORIES
2.2 PLANNING OF EXPERIMENTS AND RECORDING OF RESULTS
2.3 HAZARDS IN ORGANIC CHEMISTRY LABORATORIES
APPARATUS AND REACTION PROCEDURES
2.4 INTERCHANGEABLE GROUND GLASS JOINTS
2.5 TYPES OF GROUND GLASS JOINTS
2.6 CARE AND MAINTENANCE OF GROUND GLASS JOINTS
2.7 APPARATUS WITH INTERCHANGEABLE GROUND GLASS JOINTS SUITABLE FOR GENERAL USE IN PREPARATIVE ORGANIC CHEMISTRY
2.8 OTHER TYPES OF INTERCHANGEABLE JOINTS AND STOPCOCKS
2.9 THE USE OF CORKS AND RUBBER STOPPERS
2.10 CUTTING AND BENDING OF GLASS tubing
2.11 GENERAL LABORATORY APPARATUS
2.12 COOLING OF REACTION MIXTURES
2.13 JEATOMG PF REACTOPM MIXTIRES
2.14 MECJAMOCAL AGOTATION
2.15 TYPICAL GROUND GLASS JOINT ASSEMBLIES FOR STANDARD REACTION PROCEOURES
2.16 PRECAUTIONS FOR UNATTENEDE REACTINS
2.17 APPARATUS FOR SPECIAL REACTION TECHNIQUES
ISOLATION AND PURIFICATION PROCESSES
2.18 GENERAL CONSIDERATIONS
2.19 FILTRATION TECHNIQUES
2.20 RECRYSTALLISATION TECHNIQUES
2.21 SUBLIMATION TECHNIQUES-FREEZE DRYING
2.22 SOLVENT EXTRACTION
2.23 DRYING OF LIQUIDS OR OF SOLUTIONS OF ORGANIC COMPOUNDS IN ORGANIC SOLVENTS
2.24 DISTILLATION AT ATMOSPHERIC PRESSURE
2.25 STEAM DISTILLATION
2.26 fractional DISTILLATION AT ATMOSPHERIC PRESSURE
2.27 DISTILLATION UNDER diminished PRESSURE ('VACUUM' DISTILLATION)
2.28 HIGH VACUUM DISTILLATION - MOLECULAR DISTILLATION
2.29 VACUUM PUMPS
2.36 MANOMETERS, VACUSTATS, VACUUM GAUGES AND MANOSTATS
2.31 CHROMATOGRAPHY
2.32 STORAGE OF SAMPLES
2.33 MELTING POINT - MIXED MELTING POINTS
2.34 DETERMINATION OF BOILING POINT
2.35 DETERMINATION OF MOLECULAR WEIGHT
2.36 DETERMINATION OF OPTICAL rotatory POWER
2.37 DETERMINATION OF REFRACTIVE INDEX
REFERENCES
CHAPTER 3 SPECTROSCOPIC METHODS AND THE INTERPRETATION OF SPECTRA
Introduction
The electromagnetic spectrum
3.1 infrared SPECTROSCOPY
Instrumental features of infrared spectrophotometers
Determination of infrared spectra
Sample preparation
Features of an infrared spectrum
Interpretation of an infrared spectrum
Characteristic group frequencies
3.2 NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY
Features of the nuclear magnetic resonance spectrum
The chemical shift
Spin-spin splitting
Protons attached to heteroatoms
Simplification of 'H spectra
Interpretation of the p.m.r, spectrum
Further information from 13 C-spectra
3.3 MASS SPECTROMETRY
The mass spectrum
Appearance of the mass spectrum
Interpretation of the mass spectrum
Mass spectra of classes of organic compounds
3.4 ultraviolet-VISIBLE SPECTROSCOPY
Instrumental features of ultraviolet-visible spectrophotometers
Determination of ultraviolet-visible spectra
Laws of light absorption
Solvents for ultraviolet spectroscopy
Solution preparation
Optical cells and their care
Features of an ultraviolet-visible spectrum
REFERENCES
CHAPTER 4 SOLVENTS AND REAGENTS
4.1 THE PURIFICATION OF COMMON ORGANIC SOLVENTS
Saturated aliphatic hydrocarbons
Aromatic hydrocarbons
Halogenated hvdrocarbons
Aliphatic alcohols
Ethers
Ketones
Esters
Nitrogen-containing solvents
Sulphur-containing solvents
Phosphorus-containing solvents
4.2 THE PREPARATION AND PURIFICATION OF REAGENTS
REFERENCES
CHAPTER 5 ALIPHATIC COMPOUNDS
5.1 ALKANES
Structure
Summary of preparative methods and of retrosynthetic strategies
Spectroscopic features
5.1.1 The catalytic hydrogenation and chemical reduction of alkenes
5.1.2 The hvdrolysis of alkylmagnesium halides and the hydrogenolysis of alkyl halides and of alkyl methane- or toluene-p-suiphonates
5.1.3 The reduction of aldehydes and ketones
5.1.4 Coupling reactions (a) using organometallic compounds, and
(b) at the anode
5.2 ALKENES
Structure
Summary of preparative methods and of retrosynthetic strategies
Spectroscopic features
5.2.1 1,2-Elimination processes ([i-elimination)
5.2.2 The partial hydrogenation of aikynes
5.2.3 Wittig and related reactions
5.2.4 Selected rearrangements of alkynes to allenes
5.3 ALKYNES
Structure
Summary of preparative methods and of retrosynthetic strategies
Spectroscopicfeatures
5.3.1 The dehydrogenation of vic- and gem-dihalides
5.3.2 The oxidation of dihydrazones of 1,2-diketones
5.3.3 Aikylation of a terminal alkyne
5.3.4 Coupling reactions leading to diynes
5.4 ALIPHATIC ALCOHOLS
Structure
Summary of preparative methods and of retrosynthetic strategies
Spectroscopicfeatures
5.4.1 The reduction of aldehydes, ketones and esters
5.4.2 The interaction of carbonyl-containing compounds with organometallic reagents
5.4.3 The hydroboration-oxidation of alkenes
5.4.4 The oxymercuration-demercuration of alkenes
5.4.5 The hydroxylation of alkenes
5.4.6 Methods for the protection of the hydroxyl group
……
CHAPTER 6 AROMATIC COMPOUNDS
CHAPTER 7 SELECTED ALICYCLIC ALICYCLIC COMPOUNDS
CHAPTER 8 SELECTED HETEROCYCLIC COMPOUNDS
CHAPTER 9 INVESTIGATION AND CHARACTERISATION OF ORGANIC COMPOUNDS
CHAPTER 10 PHYSICAL CONSTANTS OF ORGANIC COMPOUNDS
APPENDICES
Table of atomic weights
Index
Reference data
Abbreviations
