研究領域
新型稀土催化劑的設計、合成與套用;選擇性有機合成方法。
代表性論文
1. Samarium Diiodide Promoted Synthesis of N,N’-Disubstituted Amidines, F. Xu, J. Sun, Q. Shen, Tetrahedron Lett. 2002, 43, 1867.
2 . One-pot Synthesis of α-Amino Phospho- nates Using Samarium Diiodide as a Catalyst Precursor, F. Xu, Y. Luo, Q. Shen, Eur. J. Org. Chem. 2003, 24, 4728.
3. Efficient Synthesis of 1,5-Benzodiazepine Derivatives by Ytterbium Trichloride-Catalyzed Condensation of o-Phenylenediamine and Ketones, J. Wu, F. Xu, Z. Zhou, Q. Shen, Synth. Commun.2006, 36, 457.
4. Facile One-pot Synthesis of α-Amino Phosphonates Using Lanthanide Chloride as Catalyst, F. Xu, Y. Luo, J. Wu, Q. Shen, H. Chen, Heteroatom Chem.2006, 17, 389.
5. Stereoselective Synthesis of Pyrano[3,2- c]- and Furano[3,2- c]Quinolines:Samarium Diiodide Catalyzed One-Pot Aza–Diels–Alder Reaction, Z. Zhou, F. Xu, X. Han, J. Zhou, Q. Shen, Eur. J. Org. Chem. 2007,5265.
6. Efficient Synthesis of Pyrimidinone Derivatives by Ytterbium Chloride Catalyzed Biginelli-type Reaction under Solvent-free Conditions, H. Zhang, Z. Zhou, Z. Yao, F. Xu, Q. Shen, Tetrahedron Lett. 2009, 50, 1622.
7. A Facile Route to 1,5-Benzodiazepine-2-ylphosphonates via Ytterbium Chloride-Catalyzed Three-Component Reaction,X. Ji, L. Cai, Z. Yao, F. Xu, Q. Shen, Heteroatom Chem. 2010, 21, 89.
8. Stereoselective Synthesis of Pyrano[3,2-c]- and Furano[3,2-c]quinolines: Gadolinium Chloride Catalyzed One-potAza-Diels-Alder Reactions, Y. Yu, J. Zhou, Z. Yao, F. Xu, Q. Shen, Heteroatom Chem. 2010, 21, 351.
9. Lanthanide Amides [(Me3Si)2N]3Ln( m-Cl)Li(THF)3 CatalyzedHydrophosphonylation of Aryl Aldehydes, Q. Wu, J. Zhou, Z. Yao, F. Xu, Q. Shen, J. Org. Chem. 2010, 75, 7498.
10. Controllable Stereoselective Synthesis of Pyrano[3,2- c]quinolines by Lanthanide Halides Catalyzed Aza-Diels-Alder Reaction, L. Yao, F. Xu, Q. Shen, Chinese Science Bulletin 2010, 55, 4108.
11.Acylation of Nitriles to β-Ketonitriles Catalyzed by Heterometal Alkoxide Cluster of Neodymium and Sodium NdNa8(OBu)10(OH), H. Liu, L. Li, H. Sheng, X. Zhu, F. Xu, Q. Shen, Chinese Science Bulletin, 2011, 56, 1357.
12. Activation of Carbodiimide and Transformation with Amine to Guanidinate Group by Ln(OAr)3(THF)2 (Ln: Lanthanide and Yttrium) and Ln(OAr)3(THF)2 as a Novel Precatalyst for Addition of Amines to Carbodiimides: Influence of Aryloxide Group, Y. Cao, Z. Du, W. Li, J. Li, Y. Zhang, F. Xu, Q. Shen, Inorganic Chemistry2011, 50, 3729.