張文魁[浙江工業大學教授]

張文魁[浙江工業大學教授]

張文魁,漢族,1969年7月出生於浙江省三門縣。浙江工業大學化工學院教授、博士生導師。

簡歷

1987.9-1991.7上海大學材料科學與工程系本科學習、獲工學學士學位;

1991.9-1994.3哈爾濱工業大學材料科學與工程系學習、獲工學碩士學位;

1994.4-1997.7 浙江大學材料系學習、獲工學博士學位;

1997.6-2002.9 講師、副教授,浙江工業大學化工學院套用化學學科方向負責人;

2002.9-至今 教授

2006.5-至今 教授、博士生導師

研究方向

1.新能源材料與先進二次電池(鎳氫電池、鋰離子電池等);

2.光電轉換與能源化學(光電催化合成,光電催化材料等);

3.有機電化學合成(醫藥中間體,精細化學品電合成);

4. 金屬功能材料和納米功能材料

科研項目

主持和參加國家自然科學基金4項、國家高技術研究發展計畫(863)1項和浙江省自然科學基金2項,同時還承擔和完成企業委託項目10多項。2002年入選浙江省“新世紀151人才工程”第二層次;2003年獲浙江省中青年學科帶頭人重點資助;2004年入選浙江省“新世紀151人才工程”第一層次、浙江工業大學青年學術帶頭人。

1.鈦鎳貯氫合金表面原位納米光催化層的形成及其光電性能,國家自然科學基金(50201016),2003.1-2005.12,29萬,項目負責人。

2.TiO2-xNx/Ni(OH)2納米複合薄膜的製備及可光充電特性,國家自然科學基金(20673100),2007.1-2009.12,28萬,排名第二。

3.定向CNTs/MTiO3(M=Sr,Ba,Ca,La)複合電極的製備及光充電嵌鋰特性,國家自然科學基金(50402020),2005.1.-2005.12,10萬,排名第二。

4.高功率MH/Ni電池電極材料的開發及其相關產業化技術,國家高技術研究發展計畫(863計畫)納米材料與微機電系統專項(2003AA302420),2003.8-2006.7,100萬,項目負責人。

5.電化學熔鹽法製備納米碳管及其形成機理研究,浙江省自然科學基金(299502),1999.1.-2003.12,4萬,項目負責人。

6.表面修飾SrTiO3貯氫合金電極的光充電貯氫特性,浙江省自然科學基金(Y404044),1999.1.-2003.12,5萬,排名第二。

7.磷酸鐵鋰動力電池產業化技術開發,企業合作項目,2008-2012,130萬,項目負責人。

8.方型大容量鋰離子動力電池產業化技術,企業合作項目,2009-2011,100萬,項目負責人。

9.5000/年電解合成丁二酸生產技術開發,山東新泰飛揚化工公司,2007-2009,50萬,項目負責人。

10.200噸/年甲基羥胺鹽酸鹽的工業化生產技術,浙江臨海華南化工有限公司,2006-02到2008-02,20萬,項目負責人。

11.300噸/年丁二酸生產技術和工藝開發,浙江建德市大洋化工有限公司,2005-11到2006-11,15萬,項目負責人。

12.不溶性Ti/Ir陽極的製備技術,浙江建德市大洋化工有限公司,2006-03到2006-12,15萬,項目負責人。

13.間接電氧化用鈰鹽媒質的再生和循環再利用技術,浙江省嘉善誠達藥化有限公司,2005-03到2006-12,20萬,項目負責人。

14.小型高能二次電池的研製,寧波力必達電池公司,2003.3~2004.12,30萬,項目負責人。

15.鋰離子電池生產工程技術服務,美國套用納米技術公司,2003.2~2004.3,20萬,項目負責人。

16.小型金屬氫化物—鎳電池研製,浙江八方建設集團,2002.1~2004.12,188萬,項目負責人。

17.羥胺鹽酸鹽電化學合成技術的工業化開發,浙江華海藥業股份有限公司,2002.6~2003.12,40萬,項目負責人。

代表性論文

[1] H. Huang, L. Jiang, W.K. Zhang, Y.P. Gan, X.Y. Tao, H.F. Chen, Photoelectrochromic properties and energy storage of TiO2-xNx/NiO bilayer thin films. Sol. Energ.Mat. Sol.C. 2010, 94: 355-359.

[2] H. Huang, S.X. Lu, W.K. Zhang, Y.P. Gan, C.T. Wang, L. Yu, X.Y. Tao, Photoelectrochromic properties of NiO film deposited on an N-doped TiO2 photocatalytical layer. J. Phys. Chem. Solids 2009, 70: 745-749.

[3] W.K. Zhang, L. Wang, H. Huang, Y.P. Gan, C.T. Wang, X.Y. Tao, Light energy storage and photoelectrochemical behavior of the titanate nanotube array/Ni(OH)2 electrode. Electrochimica Acta 2009, 54: 4760-4763.

[4] W.K. Zhang, X.Z. Zhou, X.Y. Tao, H. Huang, Y.P. Gan, C.T. Wang. In situ construction of carbon nano-interconnects between the LiFePO4 grains using ultra low-cost asphalt Electrochimica Acta 2010; 55: 2592-2596.

[5] X.Y. Tao, L.X. Dong, W.K. Zhang, X.B. Zhang, J.P. Chen, H. Huang, Y.P. Gan, Controllable melting and flow of beta-Sn in flexible amorphous carbon nanotubes. Carbon 2009, 47: 3122-3127.

[6] W.K. Zhang, C. Wang, H. Huang, Y.P. Gan, H.M. Wu, J.P. Tu, Synthesis and electrochemical properties of spinel LiCo1/6Mn11/6O4 powders by a spray-drying method, J. Alloys Compd. 2008, 465: 250-254.

[7] W.K. Zhang, X.H. Xia, H. Huang, Y.P. Gan, J.B. Wu, J.P. Tu, High-rate discharge properties of nickel hydroxide/carbon composite as positive electrode for Ni-MH batteries, J. Power Sources 2008, 184: 646-651.

[8] H. Huang, L. Zhang, W.K. Zhang, Y.P. Gan, H. Shao, Preparation and electrochemical properties of ZnO/conductive-ceramic nanocomposite as anode material for Ni/Zn battery, J. Power Sources 2008, 184: 663-667.

[9] H. Huang, C. Wang, W.K. Zhang, Y.P. Gan, L. Kang, Electrochemical study on LiCo1/6Mn11/6O4 as cathode material for lithium ion batteries at elevated temperature, J. Power Sources 2008, 184: 583-588.

[10] H. Huang, C. Wang, L. Zhang, Y.P. Gan, W.K. Zhang, Influences of sintering process of sprayed precursors on the structure and electrochemical properties of LiMn2O4 cathode material, J. Mater. Sci. & Technol. 2008, 24: 211-214.

[11] H. Shao, Y.P. Gan, H. Huang, W.K. Zhang,Electrochemical reduction behaviors of maleic acid and fumaric acid at lead electrode Acta Phys-chim Sin 2008, 24: 1264-1270.

[12] L. Zhang, H. Huang, W.K. Zhang, Y.P. Gan, C.T. Wang, Effects of conductive ceramic on the electrochemical performance of ZnO for Ni-Zn rechargeable battery, Electrochimica Acta 2008, 53: 5386-5390.

[13] X.Y. Tao, L.X. Dong, X.N. Wang, W.K. Zhang, B.J. Nelson, X.D. Li, B4C-nanowires/carbon-microfiber hybrid structures and composites from cotton T-shirts. Adv. Mater. DOI: 10.1002/adma.200903071.

[14] X.H. Xia, J.P. Tu, J. Zhang, X.H. Huang, X.L. Wang, W.K. Zhang, H. Huang, Multicolor and fast electrochromism of nanoporous NiO/poly(3,4-ethylenedioxythiophene) composite thin film. Electrochem. Commun. 2009, 11: 702-705.

[15] X.H. Xia, J.P. Tu, J. Zhang, X.L. Wang, W.K. Zhang, H. Huang, A highly porous NiO/polyaniline composite film prepared by combining chemical bath deposition and electro-polymerization and its electrochromic performance, Nanotechnology, 2008, 19: 465701.

[16] X.H. Xia, J.P. Tu, J. Zhang, X.H. Huang, X.L. Wang, W.K. Zhang, H. Huang, Enhanced electrochromics of nanoporous cobalt oxide thin film prepared by a facile chemical bath deposition, Electrochem. Commun. 2008, 10: 1815-1818.

[17] X.H. Xia, J.P. Tu, J. Zhang, X.L. Wang, W.K. Zhang, H. Huang, Morphology effect on the electrochromic and electrochemical performances of NiO thin films, Electrochimica Acta, 2008, 53: 5721-5724.

[18] X.H. Xia, J.P. Tu, J. Zhang, X.L. Wang, W.K. Zhang, H. Huang, Electrochromic properties of porous NiO thin films prepared by a chemical bath deposition, Sol. Energy Mater. Sol. C. 2008, 92: 628-633.

[19] J.B. Wu, J.P. Tu, T.A. Han, Z. Yu, W.K. Zhang, H. Huang, Electrochemical investigation on addition of CNTs to the positive electrodes for Ni/MH rechargeable batteries, J. Alloys Compd. 2008, 449: 349-352.

[20] Y.P. Gan, H. Huang, W.K. Zhang, Electrocatalytic oxidation of methanol on carbon-nanotubes /graphite electrode modified with platinum and molybdenum oxide nanoparticles, Trans. Nonferrous Met. Soc. China, 2007, 17: 214-219

[21] H. Huang, W.K. Zhang, Y.P. Gan. Improved electrochemical storage of lithium into multi-walled carbon nanotubes by light irradiation, Mater. Chem. Phys., 2007, 104: 271-275.

[22] H. Huang, W.K. Zhang, Y.P. Gan, C. Wang, L. Zhang. Electrochemical investigation of TiO2/carbon nanotubes, nonocomposite as anode materials for Li-ion batteries, Mater. Lett., 2007, 61: 196-299.

[23] H. Huang, W.K. Zhang, Y.P. Gan, L. Zhang, C. Wang. Photo-electrochemical lithum insetion of carbon nanotubes modified with SrTiO3 photocatalyst, Chin. J. Chem. Phys., 2006, 19: 428-432.

[24] J.B. Wu, J.P. Tu, W.K. Zhang, H. Huang, Electrochemical investigation on nanoscale CoO as additive to the positive electrodes for Ni/MH rechargeable batteries, J. Alloys Compd., 2007, 431: 321-325

[25] 張文魁,黃娜,黃輝, 甘永平,均勻沉澱法製備片狀結構α-Ni(OH)2,,中國有色金屬學報,2007,17:166-171.

[26] Y.P. Gan, W.K. Zhang, H. Huang, X.H. Xia, Y.S. Chen, Industrial synthesis of N-methylhydroxylamine hydrochloride by electrochemical reduction of nitromethane, Chin. J. Chem. Eng.2006, 14: 649-653

[27] 甘永平,張文魁, 黃輝, 夏新輝 ,電化學還原合成N-甲基羥胺研究, 高校化學工程學報,2006,20:437-442.

[28] 黃輝, 張文魁, 甘永平, 梁志宏. TiNi合金表面TiO2薄膜製備及光充電性能, 稀有金屬材料及工程, 2005, 34: 1890-1893

[29] H. Huang, W.K. Zhang, M.C. Li, Y.P. Gan, J.H. Chen, Y.F. Kuang.. Carbon nanotubes as a secondary support of catalyst layer in a gas diffusion electrode for metal air batteries, J. Colloid and Interface Sci., 2005, 284: 593-599

[30] 黃輝, 張文魁, 甘永平, 塗江平, 張孝彬. CNTs添加對MmMn0.4Co0.7Al0.3Ni3.4貯氫合金負極性能的影響, 無機材料學報, 2005, 20: 1139-1144

[31] 黃輝, 張文魁, 甘永平, 張孝彬, 塗江平. 納米碳管作為氧擴散電極催化層第二相碳載體的電極特性, 化學物理學報, 2005, 18: 428-432

[32] H. Huang, W.K. Zhang, M.C. Li, Y.P. Gan, C. Ma, X.B. Zhang. Electrochemical production of Sn-filled carbon nanotubes in molten salts, Trans. Nonferrous Met. Soc. China, 2004, 14: 441-445.

[33] W.K. Zhang, Y.P. Gan, H. Huang, B. Zhang, G.T. Wang, J.P. Tu. Photo-electrochemical characteristics of AB5-type hydrogen storage alloy modified with SrTiO3 photocatalyst, Trans. Nonferrous Met. Soc. China, 2005, 15: 733-737.

[34] W.K. Zhang, X.L. Tong, H. Huang, Y.P. Gan, N. Huang. Photorechargeable Properties of Metal Hydride- SrTiO3 Electrode, Chin. Chem.l Lett., 2005, 16: 979-982.

[35] 張文魁, 甘永平, 黃輝,張博, 王改田, 塗江平. 表面修飾納米TiO2的貯氫合金電極的光充電行為, 化學物理學報, 2005, 18: 832-836.

[36] 張文魁, 童希立, 黃輝,甘永平, 黃娜. 溶膠凝膠法製備鈣鈦礦型納米鈦酸鍶,中國有色金屬學報,2005, 15: 643-649.

[37] G.T. Wang, J.P. Tu, W.K. Zhang, X.L. Wang, H Huang. X.P. Gan. Photoassisted charge behavior of hydrogen storage Alloy-TiO2/Pt electrodes, J. Phys. Chem. B, 2005, 109: 13210-13213.

[38] W.K. Zhang, X.G. Yang, C. Ma, Y.G. Wang, L.Y. Yu. Crystal structure and electrochemical behaviors of Pt/mischmetal films, Trans. Nonferrous Met. Soc. China, 2003, 13: 20-24.

[39] W.K. Zhang, Y.P. Gan, X.G. Yang, H. Huang. L.Y. Yu. Crystal structure and switchable optical properties of yttrium hydride films covered by palladium layer, Trans. Nonferrous Met. Soc. China, 2003, 13: 1-5.

[40] 張文魁, 黃輝, 甘永平, 楊曉光, 余厲陽. 鈀/釔稀土系薄膜在氣態吸放氫過程中的表面形貌和可轉換光學特性, 金屬學報, 2003, 39: 974-978.

[41] 張文魁, 楊曉光, 王雲剛, 余厲陽. Pd/Mm(富鈰稀土)薄膜電極在KOH溶液中的電化學行為, 物理化學學報, 2003, 19: 569-572.

[42] 張文魁, 黃輝, 楊曉光, 雷永泉, 王啟東. 合金化對ZrMn2基Laves相貯氫合金相組成的影響, 中國有色金屬學報, 2002, 12: 897-901.

[43] 張文魁, 王雲剛, 楊曉光, 黃輝. 稀土氫化物的晶體結構及其可轉換光學特性, 稀有金屬材料與工程, 2002, 31: 432-435

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