許群[材料科學與工程教授]

許群[材料科學與工程教授]

許群,河北省武強縣人,女,1971年5月出生,教授,博士生導師。現任鄭州大學材料科學與工程學院副院長。1993年畢業於鄭州大學化學系,1996年7月碩士畢業於鄭州大學化學系;1999年9月博士畢業於中國科學院化學所;2001年8月完成德國Karlsruhe核研究中心---環境化學所博士後工作。2001年任鄭州大學材料科學與工程學院教授,博士生導師。曾獲“中國青年女科學家提名獎”美國Elsevier《Microporous and Mesoporous Materials》(影響因子:2.7)雜誌審稿人;美國化學會《crystal growth & design》(影響因子:2.7)雜誌審稿人。從事超臨界流體特性和超臨界流體在高分子化學方面的研究,發表學術論文50餘篇。

基本信息

社會兼職

美國Elsevier《MicroporousandMesoporousMaterials》(影響因子:2.7)雜誌審稿人;美國化學會《crystalgrowth&design》(影響因子:2.7)雜誌審稿人。

教育背景

1993年7月本科畢業於鄭州大學化學系;1996年7月碩士畢業於鄭州大學化學系;1999年9月博士畢業於中國科學院化學所;2001年8月完成德國Karlsruhe核研究中心---環境化學所博士後工作。

研究方向

1.以超臨界為主體的綠色化學技術在功能納米材料領域的研究;
2.功能高分子及其衍生物在能量儲藏及轉化方面的研究;
3.生物質及仿生材料的研究;
4.二維層狀材料的製備和套用研究;
5.界面的模擬計算。

科研成果

許群許群
從事超臨界流體特性和超臨界流體在高分子化學方面的研究,在熱化學、相平衡以及高分子反應、材料功能改性等研究方面具有較強的工作基礎。
回國後組建了鄭州大學的超臨界流體實驗室,開闢了超臨界流體中合成材料的新領域,首次發現了超臨界流體對材料表面的誘導結晶現象,研究結果在寄出不到一個月即被發表在Chemistryletter即<<日本化學快報>>上。
發表學術論文50餘篇,其中SCI收錄論文近30篇,其中一篇的研究結果被JournalofAppliedPolymerScience即<<美國套用聚合物科學>>引為雜誌封面。
目前主持項目有國家自然科學基金教育部歸國留學人員基金、河南省傑出青年基金、河南省國際合作項目等。
獲得的獎項有中國化學會優秀論文獎、河南省自然科學優秀論文一等獎和二等獎。
發表專著有中國化學工業出版社出版的《環境、化學與可持續發展》和英國劍橋出版社出版的《Biodegradablepolymersforindustrialapplications》的Chapter18“Generationofbiodegradablepolycaprolactonefoamsinsupercriticalcarbondioxide”。
材料工程學院許群教授及其課題組在研究碳納米管的修飾時,發現了一種新技術“超臨界二氧化碳作為抗溶劑誘導聚合物結晶從而修飾碳納米管”,他們的研究方法增加了碳納米管與聚合物基體的界面結合力,確定碳納米管良好分散性的同時,還保證了碳納米管固有的獨特性能。這一研究在該學術領域引起了人們的極大興趣,從2007年起,國際著名學術期刊Macromolecules即美國《大分子》,和JournalofPhysicalChemistry即美國《物理化學》陸續發表他們的工作(Macromolecules,2007,40,8821;Macromolecules,2008,41,2868;Macromolecules,2008,41,4519;J.Phys.Chem.C,2009,113,18531),僅2010年上半年美國《物理化學》就發表了4篇他們的研究成果(J.Phys.Chem.B,2010,114,5257;J.Phys.Chem.B,2010,114,9435;J.Phys.Chem.C,2010,114,10119;J.Phys.Chem.C,2010,114,12728),與此同時《中國科學》也發表了他們的研究成果(中國科學B,2010,53,1525)。
令人欣喜的是,最近他們有關共軛高分子修飾碳納米管的研究,被美國化學會列為7月份當周世界上最為突出六項化學研究成果之一,這充分顯示了我校在該領域的研究達到了國際先進水平。

榮譽與獎勵

2004年獲“河南省學術與技術帶頭人”稱號;
2005年被評為河南省首屆歸國留學人員創業之星;
2006年評為河南省高校優秀共產黨員;
2006年獲河南省師德標兵榮譽稱號;
2006年“利用超臨界流體技術對工程塑膠進行改性”獲河南省科技進步二等獎;
2007年獲河南省青年科技專家榮譽稱號;
2008年獲中國青年女科學家獎提名獎;
2009年獲日本化學會亞洲傑出學者獎;
2009年獲國務院政府特殊津貼;
2009年獲河南省五四青年獎章;
2010年獲寶鋼優秀教師獎;
2011年所帶領團隊獲河南省科技創新團隊;
2013年“綠色化學手段製備功能性材料及其套用”獲河南省科技進步二等獎。

代表性論文

2014年

1.LianrenHu,YumeiRen,HongxiaYang,QunXu*,“Fabricationof3DHierarchicalMoS2/PolyanilineandMoS2/CArchitecturesforLithium-IonBatteryApplications”,ACSAppliedMaterials&Interfaces,2014,6,14644-14652.
2.ShoupeiWang,JiananZhang,*PeiShang,YuanyuanLi,ZhiminChen,QunXu*,“Carbonsphereswithhierarchicalmicropore-nanosheetnetworksforhighperformancesupercapacitors”,Chem.Commun.2014,DOI:10.1039/C4CC04832F.
3.JiananZhang,KaixiWang,ShaojunGuo*,ShoupeiWang,ZhiqiangLiang,ZhiminChen,JianweiFu,QunXu*,“One-StepCarbonizationSynthesisofHollowCarbonNanococoonswithMultimodalPoresandTheirEnhancedElectrochemicalPerformanceforSupercapacitor”,ACSAppliedMaterials&Interfaces,2014,6,2192-2198.
4.YumeiRen,QunXu*,JianminZhang,HongxiaYang,BoWang,DaoyuanYang,JunhuaHu,ZhiminLiu*,“FunctionalizationofBiomassCarbonaceousAerogels:SelectivePreparationofMnO2@CACompositesforSupercapacitors”,ACSAppliedMaterials&Interfaces,2014,2014,6,9689-9697.
5.DongdongXu,QunXu*,KaixiWang,JunChen*,ZhiminChen,“FabricationofFree-standingHierarchicalCarbonnanofiber/Grapheneoxide/PolyanilinefilmsforSupercapacitors”,ACSAppliedMaterials&Interfaces,2014,6,200-209.
6.ShanshanXu,HongxiaYang,KaixiWang,BoWang,QunXu*,“EffectofSupercriticalCO2onFabricationofFree-standingHierarchicalGrapheneoxide/Carbonnanofiber/PolypyrrolefilmanditsElectrochemicalProperty”,PCCP,2014,16,7350-7357.
7.YumeiRen,JianminZhang,QunXu,*ZhiminChen,DaoyuanYang,BoWangandZhengJiang*,“Three-dimensionalPorousN-dopedCarbonaceousAerogelforEfficientSupercapacitorElectrodes”,RSCAdv.,2014,4,23412–23419.
8.JiananZhang,XianglanZhang,YunchunZhou,ShaojunGuo,KaixiWang,ZhiqiangLiang,QunXu*,“Nitrogen-DopedHierarchicalPorousCarbonNanowhiskerEnsemblesonCarbonNanofiberforHigh-PerformanceSupercapacitors”,ACSSustainableChemistry&Engineering,2014,2,1525-1533.
9.ZhonghuiChen,JianweiFu*,MinghuanWang,XuzheWang,JiananZheng,QunXu*,“Adsorptionofcationicdye(methyleneblue)fromaqueoussolutionusingpoly(cyclotriphosphazene-co-4,4′-sulfonyldiphenol)nanospheres”,AppliedSurfaceScience,2014,289,495-501.
10.ZhonghuiChen,JiananZhang,JianweiFu*,MinghuanWang,XuzheWang,RunpingHan,QunXu*,“Adsorptionofmethyleneblueontopoly(cyclotriphosphazene-co-4,4_-sulfonyldiphenol)nanotubes:Kinetics,isothermandthermodynamicsanalysis”,JournalofHazardousMaterials,2014,273,263-271.11.KakaZhang,JingWang*,YanjinWang,LiangZhao,QunXu*,“Facilehigh-yieldsynthesisofpoly(aniline-co-m-sulfophenylenediamine)forcationicdyeremoval”,ChemicalEngineeringJournal,2014,247,50-58.
12.XuzheWang,JianweiFu*,MinghuanWang,YajieWang,ZhiminChen,JiananZhang,JiafuChen,QunXu*,“FacilesynthesisofAunanoparticlessupportedonpolyphosphazenefunctionalizedcarbonnanotubesforcatalyticreductionof4-nitrophenol”,JMater.Sci,2014,49,5056–5065.
13.BoWang,ZhiminChen*,JingjingCao,QunXu,*“FabricationofPVA/GrapheneOxide/TiO2CompositeNanofibersthroughElectrospinningandInterfaceSol-GelReaction:EffectofGrapheneOxideonPVANanofibersandGrowthofTiO2”,ColloidsandSurfacesA:PhysicochemicalandEngineeringAspects,2014,accepted.
14.YangLiu,JiananZhang*,ShoupeiWang,KaixiWang,ZhiminChen,QunXu*,“Facilelyconstructing3DporousNiCo2S4nanonetworksforhighperformancesupercapacitors”,NewJournalofChemistry,2014,38,4045-4048.
15.JianweiFu,ZhonghuiChen,MinghuanWang,QunXu*,“Adsorptionofmethylenebluebyahigh-efficiencyadsorbent(polydopaminemicrospheres):Kinetics,isotherm,thermodynamicsandmechanismanalysis”,ChemicalEngineeringJournal,2014,DOI:10.1016/j.cej.2014.07.101.
16.ZhiminChen,JiananZhang,YuanlongGuo,HaoZhang,JingjingCao,QunXu*,ShuxiaWang,BoWang,ZhaotieLiu,“EffectsofvariousfactorsonthemodificationofcarbonnanotubeswithpolyvinylalcoholinsupercriticalCO2andtheirapplicationinelectrospunfibers”,ChemicalResearchinChineseUniversity,2014,4,690-697.

2013年

17.JiananZhang,ShaojunGuo*,JunyiWei,QunXu*,JianweiFu,ShoupeiWang,MingjingCao,ZhiminChen,“High-efficiencyencapsulationofPtnanoparticlesintothechannelofcarbonnanotubesasanenhancedelectrocatalystformethanoloxidation”,Chemistry-AEuropeanJournal,2013,19,16087-16092.
18.GuihengXu,QunXu*,AnjunQin,JingtaoCheng,NanWang,JunyiWei,ChengliangZhang,ZhenzhongYang*,BenZhongTang*,“ImmobilizationofPolymericFluorogenonPDVBNanotubewithAssistanceofSupercriticalCO2forFunctionalFilms”,J.Mater.Chem.C,2013,1,1717–1721.
19.MinghuanWang,JianweiFu*,DandanHuang,ChaoZhang,QunXu*,“Silvernanoparticles-decoratedpolyphosphazenenanotubes:synthesisandapplications”,Nanoscale,2013,5,7913-7919.
20.GuihengXu,DongdongXu,JiananZhang,KaixiWang,ZhiminChen,JiafuChen,QunXu*,“ControlledFabricationofPANI/CNFHybridFilms:MolecularInteractionInducedVariousMicromorphologiesandElectrochemicalProperties”,J.ColloidIntersurf.Sci.2013,411,204-212.
21.JiafuChen,ZhanlinLang,QunXu*,JiananZhang,JianweiFu,ZhiminChen,“ANovelMethodtoFabricateDiscretePorousCarbonHemispheresandTheirElectrochemicalPropertiesasSupercapacitors”,PCCP,2013,15,17786–17792.
22.LihuaLi,XiaoliZheng,JianjunWang,QiangSun,QunXu*,“Solvent-ExfoliatedandFunctionalizedGraphenewithAssistanceofSupercriticalCarbonDioxide”,ACSSustainableChemistry&Engineering,2013,1,144-151.
23.LihuaLi,JiananZhang,YuqingLiu,WeiminZhang,HongxiaYang,JunChen,QunXu*,“FacileFabricationofPtNanoparticleson1-PyrenamineFunctionalizedGrapheneNanosheetsforMethanolElectrooxidation”,ACSSustainableChemistry&Engineering,2013,1,527-533.
24.LeileiLv,QunXu*,RuiDing,LiQi,HongyuWang,“ChemicalsynthesisofmesoporousCoFe2O4nanoparticlesaspromisingbifunctionalelectrodematerialsforsupercapacitors”,MaterialsLetter,2013,111,35-38.
25.ZhiminChen,JianweiFu,QunXu*,YuanlongGuo,HailianZhang,JiafuChen,JiananZhang,GuoTian,BaiYang*,“SterichindrancecolloidalmicrosphereapproachtofabricateorderedandinterconnectedPtorPt/Aghollowhemispheres”,J.ColloidIntersurf.Sci.2013,392,54-59.
26.ShanshanWang,ZhiminChen*,HailianZhang,QunXu*,"SynthesisandStructuralEvolutionofHollowFlower-typeMesoporousSilicamicrospheres",JournalofMaterialsScience,2013,48,2268-2276.
27.JunyiWei,JiananZhang,YangLiu,GuihengXu,ZhiminChen,QunXu*,“ControlledGrowthofWhisker-likePolyanilineonCarbonNanofibersandTheirLongCycleLifeforSupercapacitor”,RSCAdvances,2013,3,3957-3962.
28.JianweiFu*,MinghuanWang,ChaoZhang,XuzheWang,HongfangWang,QunXu*,“Template-inducedcovalentassemblyofhybridparticlesforthefacilefabricationofmagneticFe3O4–polymerhybridhollowmicrospheres”,JournalofMaterialsScience,2013,48,3557-3565.
29.XuzheWang,MinghuanWang,JianweiFu*,ChaoZhang,QunXu*,“Facilefabricationofcore–shellstructuredmagneticFe3O4/cross-linkedpolyphosphazenenanocompositeparticleswithhighstability”,JournalofNanoparticlesresearch,2013,15,1853-1859.
30.JiafuChen,ZhanlinLang,QunXu*,BoHu,JianweiFu,ZhiminChen,JiananZhang,“FacilePreparationofMonodisperseCarbonSpheres:Template-FreeConstructionandTheirHydrogenStorageProperties”,ACSSustainableChemistry&Engineering,2013,1,1063-1068.

2012年

31.XiaoliZheng,QunXu*,JianboLi,LihuaLi,JunyiWei,“High-Throughput,DirectExfoliationofGraphitetoGrapheneviaaCooperationofSupercriticalCO2andPyrene-polymers”,RSCAdvances,2012,2,10632–10638.
32.LinghaoHe,XiaoliZheng,QunXu*,ZhiminChen,JianweiFu,“ComparisonStudyofPEEpitaxyonCarbonNanotubesandGrapheneOxideandPE/GrapheneOxideasAmphiphilicMolecularStructureforSolventseparation”,AppliedSurfaceScience,2012,258,4614-4623.
33.GuihengXu,NanWang,JunyiWei,LeileiLv,JiananZhang,ZhiminChen,QunXu*,“PreparationofGrapheneOxide/PolyanilineNanocompositewithAssistanceofSupercriticalCarbonDioxideforSupercapacitorElectrodes”,Ind.Eng.Chem.Res.2012,51,14390-14398.
34.JianweiFu,MinghuanWang,ChaoZhang,PengZhang,QunXu*,“Highhydrogenstoragecapacityofheteroatom-containingporouscarbonnanospheresproducedfromcross-linkedpolyphosphazenenanospheres”,MaterialsLetter,2012,81,215-218.
35.JianweiFu*,MinghuanWang,ChaoZhang,QunXu*,XiaobingHuang,XiaozhenTang,“Controlledfabricationofnoblemetalnanoparticlesloadedonthesurfacesofcyclotriphosphazene-containingpolymernanotubes”,JournalofMaterialsScience,2012,47,1985-1991.

2011年

36.NingYu,XiaoliZheng,QunXu*,LinghaoHe,“Controllable–InducedCrystallizationofPE-b-PEOonCarbonNanotubeswithAssistanceofSupercriticalCO2:EffectofSolvent”,Macromolecules,2011,44,3958-3965.
37.NingYu,LinghaoHe,YuanyuanRen,QunXu*,“High-CrystallizationPolyoxymethyleneModificationonCarbonNanotubeswithAssistanceofSupercriticalCarbonDioxide:MolecularInteractionsandTheirThermalStability”,Polymer,2011,52,472-480.
38.XiaoliZheng,QunXu*,LinghaoHe,NingYu,ShanshanWang,ZhiminChen,JianweiFu,“ModificationofGrapheneOxidewithAmphiphilicDouble-CrystallineBlockCopolymerPolyethylene-b-poly(ethyleneoxide)withAssistanceofSupercriticalCO2anditsFurtherFunctionalization”,J.Phys.Chem.B,2011,115,5815-5826.
39.QiuyanYang,JiafuChen,QunXu*,LinghaoHe,ZhiminChen,JianweiFu,“SphericalAssembledMicrostructures:FabricationandTheirStabilizationwithAssistanceofSupercriticalCarbonDioxide”,SoftMatter,2011,7,5353-5359.
40.QiuyanYang,JiafuChen,LibinWang,QunXu*,LinghaoHe,“MorphologyControland2DSelf-AssemblyofPoly(styrene-co-divinylbenzene)Capsules”,JournalofColloidandInterfaceScience,2011,358,437-443.
41.LinghaoHe,JingSun,XiaoliZheng,QunXu*,RuiSong,“Effectofmultiwalledcarbonnanotubesoncrystallizationbehaviorofpoly(vinylidenefluoride)indifferentsolvents”,J.Appl.Poly.Sci.,2011,119,1905-1913.
42.ZhiminChen,FengfengXue,QunXu*,"EffectofSupercriticalCO2onThreeDimensional(3D)ColloidArraysofPS-MA–EGDMA",J.Appl.Poly.Sci.,2011,119,2393-2399.
43.JianweiFu,ZhiminChen,QunXu*,JiafuChen,XiaobinHuang,XiaozhenTang,“Theproductionofporouscarbonnanofibersfromcross-linkedpolyphosphazenenanofibers”,Carbon,2011,49,1037-1039.
44.JianweiFu*,MinghuanWang,ShitaoWang,XuzheWang,HongfangWang,LeiHu,QunXu*,“Supercriticalcarbondioxide-assistedpreparationofpalladiumnanoparticlesoncyclotriphosphazene-containingpolymernanospheres”,AppliedSurfaceScience,2011,257,7129-7133.
45.GuannanSun,ZhiminChen*,ShanshanWang,LinmeiLi,JianweiFu,JiafuChen,QunXu*,“Preparationofhollowsilicamicrosphereswithcontrolledshellthicknessinsupercriticalfluids”,ColloidPolym.Sci.,2011,289,1397-1406.
46.JiafuChen,YanLi,FengfengXue,ZhiminChen,QunXu*,“PreparationofPolystyreneParticleswithDifferentMorphologies”,PolymerEngineering&Science,2011,51(6),1170-1177.
47.JianweiFu,QunXu,“RapidSynthesisofCyclomatrixPolyphosphazeneSpheresandtheirApplicationfortheProductionofMicroporousCarbonSpheres”,AdvancedMaterialsResearch,2011,266,188-191.

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