康北笙

近年來開展低維和三維功能超分子化合物和分子聚集體的研究,包括合成,結構,譜學及物理化學性質如光,電,磁等性質。 曾主持或主要參加十多項包括國家攀登、國家自然科學基金重大、重點、面上、科學院“七五”、“八五”重大、以及國家重點實驗室、省自然科學基金,博士點基金等項目。 發表學術論文300餘篇,參與三本國內外出版專著的編寫。

基本信息

個人簡歷

康北笙,女。浙江嘉興人。1963年畢業於台灣大學化學系。1967年獲美國芝加哥大學哲學博士學位。後在聯邦德國、義大利深造。1972年回國,歷任中國科學院福建物質結構研究所副研究員、結構化學研究室合成組組長、結構一室主任,福建省科協副主席,福建省第六、七屆人大常委會副主任。是第五屆全國政協委員。

主要學術經歷

先後在美國紐約大學,布魯克海汶國家實驗室,德國卡爾斯魯大學進行博士後研究。

1972年回國,在中國科學院福建物質結構研究所工作。1995年調入中山大學。

曾任職位

康北笙教授曾任福建省人民代表大會常務委員會副主任(六,七屆)。

全國政協委員(五屆),全國青年聯合會五屆委員。

福建省科協二,三,四屆副主席,中國科協四屆委員會委員。

現任職位

中國化學會理事,中國科學院福建物質結構研究所研究員。

香港中文大學客座教授,《結構化學》副主編等職。

現任國務院學位委員會學科評議組成員。

上海金屬有機國家重點實驗室學術委員會副主任。

廣東省化學會副理事長,校學術委員會學位委員會委員。

《化學通報》、《中山大學學報(自然科學版)》編委等職。

教學成績

曾為研究生開設《金屬有機化學》,《現代物理化學專題》等專業課,為本科生介紹《固氮酶及其化學模擬》。

目前為本科生講授《化學專業英語》。

已培養二十餘名博士後,博士生,和碩士生。

多次獲中國科學院自然科學獎。

科研成果獲獎情況

1. 固氮酶活性中心模擬物的研究-福州模型的試探合成 中國科學院科技成果獎 一等 4 1979.

2. 同上 福建省科技成果獎 一等 4 1980.

3. 單齒硫醇配位的鉬硫化合物的合成及鑑定 中國科學院科技成果獎 三等 2 1979.

4. 固氮酶活性中心模擬物合成中的籠格效應 中國科學院科技成果獎 三等 3 1983.

5. 鉬鐵硫(氧)鏈狀化合物研究 中國科學院自然科學獎 三等 2 1989.

6. 過渡金屬原子簇化合物的合成化學和結構化學 中國科學院自然科學獎 一等 8 1991.

7. 同上 國家自然科學獎 二等 8 1993.

8. 多核過渡金屬簇(配)合物及其協同效應和簇骼轉換 中國科學院自然科學獎 一等 1 1993.

9. 固相配位化學反應及原子簇合成 國家教委科技進步獎 一等 9 1995.

論文(中大第一單位)

1. Chen,Z. N.,Li,W. J.,Kang,B. S.,Hong,M. C.,Zhou,Z. Y.,Mak,T. C. W.,Lin,Zhang,Chen,X. M.,Liu,H. Q.,Heterooctanuclear cluster complex formation with phosphine-participation: Synthesis,structure,and magnetic properties of Co6Ru2(mp)10(PBu3)6,Inorg. Chem.,1997,36,(2) 208-213.

2. Chen,Z. N.,Kang,B. S.,Yu,K. B.,Tong,Y. X.,Zhang,H. X.,Su,C. Y.,Reactions of Transition metal thiolato units. Part III. The formation and characterization,structural regularity of building block complex [HNEt3][Ni(mp)(Hmp)(PBu3)] and its construction product Ni2Ru(mp)3(Hmp)(PBu3)2,Science in China B,1997,(Eng) 40 (6),634-642.

3. Kang,B. S.,Tong,Y. X.,Shi,J. C.,Liu,J. P.,Liu,G. K.,手性膦配位鈀化合物的電化學性質,Electrochemical Properties of Palladium(II) Complexes with Chiral Phosphine Ligands Derived from Sugars,Acta Sci. Natur. U. Sunyatseni,(中山大學學報自然科學版) 1997,36(2),68-71.

4. Kang,B. S.,Chen,Z. N.,Tong,Y. X.,Liu,H. Q.,Gao,H. R.,Wu,B. M.,Mak,T. C. W.,Syntheses and X-ray structural characterization of phosphine cobalt (II) complexes with 2-mercaptobenzothiazole,Polyhedron,1997,16(10),1731-1737.

5. Chen,Z. N.,Zhang,H. X.,Yu,K. B.,Kang,B. S.,Extended network via axial Cu-Br linkages of zig-zag coordination chains of copper(II) ions bridged alternatively by trans-oxamidate and end-on azide groups,Chem. Lett.,1998,(3),275-27.

6. Chen,Z. N.,Li,W. J.,Kang,B. S.,Wu,B. M.,Mak,T. C. W.,Cai,Y. B.,Synthesis,crystal structure,and magnetic properties of an asymmetric,mixed valence,tetranuclear complex CoII3CoIII(mp)4(Hmp)(PMePh2)3 with 2-mercaptophenol and dimethylphenylphosphine ligands,J. Coord. Chem.,1998,44(1-2),33-45.

7. Chen,Z. N.,Li,W. J.,Kang,B. S.,Zhang,H. X.,Zhou,Z. Y.,Mak,T. C. W.,Cai,Y. B.,Hong,M. C.,Liu,H. Q.,Synthesis,structure,and magnetic properties of a cyclic heterotetranuclear complex Co3Fe(mp)4(Hmp)(PBun3)3 of 2-mercaptophenol with tri-n-butylphosphine participation,J. Chi. Chem. Soc.,(中國化學會會志) 1998,45 (3),367-373.

8. Chen,Z. N.,Zhang,H. X.,Kang,B. S.,Sun,J.,Syntheses and crystal structures of two cobalt(III) complexes Co(pym)2(PBun3)2 and Co(tpym)2(PBun3)2 with mixed phosphine and N-heterocyclic thiolato ligands,Syn. Reac. Inorg. Metal-Org. Chem.,1998,28(2),245-261.

9. Chen,Z. N.,Zhang,H. X.,Yu,B. S.,Su,C. Y.,Kang,B. S.,A trinuclear Nickel(II) complex with alternating square-planar and octahedral geometires. Synthesis,crystal structure and magnetic properties of [Ni3(oxen)2(en)][ClO4]2,Polyhedron,1998,17 (9),1535-1540.

10. Chen,Z. N.,Siu,A.,Su,C. Y.,Williams,I.,Kang,B. S.,fac-triazido(2,2¢-Biypridine-N,N')(Pyridine-N)Cobalt(III),Acta Cryst.,1998,C54,479-481.

11. Chen,Z. N.,Zhang,H. X.,Yu,K. B.,Zheng,K. C.,Cai,H.,Kang,B. S.,Extended network via hydrogen bond linkages of zig-zag coordination chains [{Cu2(trans-oxen)(m-OH)( m-H2O)}n]n+ or [Cu2(trans-oxen)( m-OCN)2]n [H2oxen = N,N'-bis(2-aminoethyl)oxamide],J. Chem. Soc. Dalton Trans.,1998,(7),1133-1136.

12. Chen,Z. N.,Zhang,H. X.,Su,C. Y.,Zhou,Z. Y.,Zheng,K. C.,Kang,B. S.,Two-dimensional sheets of rugged hexagonal grids of [Cu6(trans-oxen)3(m3-OH)2(H2O)2]n4+ with Cu(II) bridged by trans-oxen and m3-OH groups,Inorg. Chem.,1998,37 (15),3877-3880.

13. Chen,Z. N.,Kang,B. S.,Yu,K. B.,Lin,Z.,Hong,M. C.,Tong,Y. X.,Zhang,H. X.,Su,C. Y.,Reactions of Transition metal thiolato units. Part III. Building block complex [HNEt3][Ni(mp)(Hmp)(PBun3)] and the formation,characterization,and structural regularity of its construction product Ni2Ru(mp)3(Hmp)(PBun3)2,Science in China B,1998,(Chi) 28 (1),15-23.

14. Chen,Z. N.,Zhang,H. X.,Kang,B. S.,Zhou,Z. Y.,Li,W. J.,Tong,Y. X.,Su,C. Y.,A triangular cobalt-phosphine-aminothiolato complex of sulfur-capping: synthesis,structure and properties of Co3(m3-S)(abt)3(PBun3)3,Bull. Chem. Soc. Jpn.,1998,71,(8),1805-1809.

15. Chen,Z. N.,Zhang,H. X.,Yu,K. B.,Kang,B. S.,Cai,H.,Su,C. Y.,Wang,T. W.,Lu,Z. L.,3D-extended supramolecular structures via H-bonded linkages of 2D sheet-like or 1D zig-zag coordination polymers,Inorg. Chem.,1998,37(19),4775-4781.

16. Kang,B. S.,Chen,Z. N.,Su,C. Y.,Zheng,K. C.,Liu,H. Q.,Zhou,Z. Y.,Crystal and molecular structure of Co6S8(PBu3)6 and synergism in the cluster core M6E8P6 (E = S,Se,Te),Chem. J. Chi. Univ.,高等學校化學學報,1998,19,(5),760-764.

17. Kang,B. S.,Chen,Z. N.,Gao,H. R.,Zhou,Z. Y.,Wu,B. M.,Mak,T. C. W.,Lin,Z.,Syntheses and structural regularities of mixed bidentate phosphine and bidentate thiolato complexes of cobalt and nickel,Acta Chim. Sinica,1998,56(1),58-67.

18. Kang,B. S.,Chen,Z. N.,Su,C. Y.,Lin,Z.,Wen,T. B.,Reactions of Transition metal thiolato units. Part V. Formation of a binuclear Mercury(II) complex with the dithiolato ligand i-mnt (1,1-dicyanoethylene-2,2-dithiolate),Polyhedron,1998,17(15),2497-2505.

19. Kang,B. S.,Zheng,K. C.,Zhang,H. X.,Tong,Y. X.,Wen,T. B.,Cao,R.,Synthesis and Structure of Pd(Hmp)2(PBu3)2,and the mechanism of its dimerization,Acta Phys.-Chim. Sin.,物理化學學報,1998,14(8),725-730.

20. Wen,T. B.,Kang,B. S.,Wu,D. X.,Su,C. Y.,Wang,L. G.,Liao,S.,Liu,H. Q.,Chemistry of o-mercaptophenolate: syntheses,structures,and characterization of titanium(IV) complexes,Bull. Chem. Soc. Jpn.,1998,71(10),2339-2343.

21. Lu,Z. L.,Kang,B. S.,Fun,H. K.,Razak,I. A.,Chinnakali,K.,o-Chlorobenzaledhyde nicotinoylhydrazone dihydrate,Acta Cryst. 1999,C55,89-91.

22. Kang,B. S.,Chen,Z. N.,Lin,Z.,Zhang,H. X.,Liu,H. Q.,Huang,X. Y.,Reactions of transition metal thiolato units IV. Formation of phosphine-containing cobalt or nickel complexes with i-maleonitrile-thiolate,J. Coord. Chem.,1999,46(4),409-424.

23. Kang,B. S.,Wen,T. B.,Yu,X. Y.,Zhang,H. X.,Yong,Y. X.,Su,C. Y.,Chen,Z. N.,Liu,H. Q.,Integrity and structural characteristics of the M6E8 core and the syntheses and structures of [Co6S8(PR3)6]n+ (R3 = Me2Ph,n = 1 (1); R = OMe,n = 0 (2)),J. Cluster Sci.,1999,10(3) 429-443.

24. Kang,B. S.,Wang,X. J.,Su,C. Y.,Liu,H. Q.,Wen,T. B.,Liu,Q. T.,Vanadium chemistry of o-mercaptophenol. Part IV*. Construction of heterobinuclear complexes via the synthon [V(mp)3]2- (mp = o-mercaptophenolato dianion). Syntheses and structures of (BzMe3N)2[V(mp)3] × MeCN × 1/2 MeOH and V-Co Complexes,Trans. Met. Chem.,1999,24(6),712-717.

25. Wang,X. J.,Chen,Z. F.,Kang,B. S.,Liang,H.,Liu,H. Q.,Yu,K. B.,Su,C. Y.,Chen,Z. N.,Chemistry of o-mercaptophenol (H2mp). Part III. One dimensional arrays of binuclear anions of Mo(VI) linked by Hmp-mpH via hydrogen bondings,Polyhedron,1999,18(5),647-655.

26. Wang,X. J.,Kang,B. S.,Su,C. Y.,Yu,K. B.,Zhang,H. X.,Chen,Z. N.,Function of H-bond in the conversion of a- to b-Mo8O264- ions. Formation and structure of tetra(tributylhydrogenammonium) b-octamolybdate,Polyhdron,1999,18(26),3371-3375.

27. Xiao,W.,Lu,Z. L.,Deng,L. R.,Su,C. Y.,Kang,B. S.,Synthesis and characterization of a new tripodal ligand containing ferrocenyl group,Acta Sci. Natur. Univ. Sunyatseni,中山大學學報(自然科學版),1999,38(5),127-128.

28. Xiao,W.,Lu,Z. L.,Li,R. Y.,Su,C. Y.,Kang,B. S.,S. Shanmuga,S. Raj,H.-K. Fun,1,1'-Diacetylferrocene bis(thiosemicarbazone) monohydrate,Acta Cryst.,1999,C55,1762-1764.

29. Zhang,H. X.,Chen,Z. N.,Yu,K. B.,and Kang,B. S.,Syntheses and crystal structures of two oxamidato-bridged dicopper complexes,Inorg. Chem. Commun.,1999,2 (6),223-235.

Resume(英文簡歷)

Name: Kang,Bei-Sheng (female),Born 1941.10.2,married,two children

EDUCATION

Sept. 1959 to June 1963 B.S. Department of Chemistry,National Taiwan University

March 1964 to Dec. 1967 Ph.D. Department of Chemistry University of Chicago

ACADEMIC PROFESSION

March 1964-Dec. 1967 Research Assistant Department of Chemistry,University of Chicago

Dec. 1967-May 1969 Post-doctorate Department of Chemistry,New York University

June 1969-Sept. 1969 Visiting Research Dep. of Chemistry,Brookhaven National Laboratory

Nov. 1969-Dec. 1970 Post-doctorate Organic Chemistry Institute,Karlsruhe University,

Oct. 1972-May 1973 Lecturer Department of Chem. and Chem. Engineering

Fuzhou University

May 1973-Feb. 1995 Professor Fujian Insitute of Research on the Structure of

Matter,Chinese Academy of Sciences

July 1992-June 1995 Honorary visiting Department of Chemistry

Professor The Chinese University of Hong Kong

Jan. 2001.1- Honorary professor Department of Biological Chemistry & Chemical

Technology,The Hong Kong Polytechnic University

March 1995-present Professor School of Chemistry and Chemical Engineering

Sun Yat-Sen University,Guangzhou,China

1999.6- Part-time professor Department of Chemistry,Henan Normal University

OTHER PROFESSION

2000- editorial board member

1987-1995 Deputy editor-in-chief (Chi. J. Strucutral Chemistry)

1988-present Vice chairman Academic Advisory Board

State Key Laboratory of Organometallic Chemistry

Shanghai Institute of Organic Chemistry

1993.11-1997.10 member Evaluation Committee of Chemistry

Chinese Academy of Sciences

May 1997- member Evaluation Committee of Chemistry

National Advisory Council of Higher Degrees

June 1997- Vice chairman Chemical Society of Guangdong Province

RESEARCH INTEREST

Syntheses,structures and physico-chemical properties of transition metal coordination complexes,cluster compounds,and supramolecular complexes,including crystal structural,spectroscopical,electrochemical,and magnetic investigations. Structural regularities are studied,cluster formation mechanisms are interpreted,and crystal engineering processes are investigated via unit construction processes of simple structural units (building blocks)----mononuclear stable or metastable complexes or intermediates.

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