個人簡介
侯召民,男抄,國家高層次“千人計畫”學者,現任大連理工大學化工學院教授自。
主要學歷
1978-1982年 中國石油大學 煉製系 本科
1984-1986年 日本九州大學 套用化學專業 碩士
1986-1989年 日本九州大學 套用化學專業 博士
工作經歷
1989-1990年 日本理化學研究所 有機金屬化學研究室 博士後
1991-1993年 加拿大溫莎大學 化學系 博士後
1993-1996年 日本理化學研究所 有機金屬化學研究室 研究員
1997-2002年 日本理化學研究所 有機金屬化學研究室 副主任研究員
2003-2007年 日本科學技術振興機構(JST)創新團隊 研究員
2004-2007年 日本千葉大學 客座教授
2005-2005年 法國路易·巴斯德大學 客座教授
2008-2011年 大連理工大學 長江學者講座教授
2002-present 日本理化學研究所 有機金屬化學研究室 主任研究員
2003-present 日本埼玉大學 客座教授
2004-present 北京大學 客座教授
2006-present 中國科學院長春套用化學研究所 客座教授
2008-present 日本東京工業大學 客座教授
2011-present 大連理工大學 國家高層次“千人計畫”學者 大連理工大學教授
社會兼職
日本化學會會員,日本有機合成化學協會會員互,日本高分子化學會會員,日本催化學會會員動,日本配位化學會會員,日本稀土學會會員,美國化學會會員,英國皇家化學會會員(Fellow, FRS),日本稀土學會理事。
研究領域(研究課題)
1. "新穎稀土催化劑的開發" 日本學術振興會基盤研究(S)
2. "綠色化學研究" 日本理化學研究所基礎科學研究課題
3. "稀土氫簇的合成及其催化作用" 日本文部科學省科研費特定領域研究
4. "環境分子科學研究" 日本理化學研究所基礎科學研究課題
5. "d-f混合過渡金屬配位化合物的合成及其反應" 日本科學技術振興機構戦略創造研究推進事業先驅型研究
6. “利用新型稀土催化劑進行新型聚合反應的開發” 日本文部科學省特定領域研究
7. “稀土聚烯烴催化劑的開發和套用”日本學術振興會基盤研究(A)
8. 多項國際合作項目
碩博研究方向
催化劑是有機合成化學、烯烴聚合化學和材料化學等研究領域的關鍵和核心,改變催化劑可以得到特定結構和性能的產物。我們以“新催化劑,新反應,新材料”為宗旨,致力於開發新型的、高效高選擇性的、具有自主智慧財產權的稀土金屬有機配合物,並探索其在精細化工合成、小分子活化、烯烴聚合、材料開發等方面的催化作用,開發具有廣泛工業套用前景的新材料。目前的研究課題主要包括:
1. 開發新穎、高效和高選擇性的烯烴聚合催化劑,獲得結構新穎性能優異的高分子材料。
2. 開發新穎、高效和高選擇性的有機合成催化劑,提高有機合成反應的催化效率。
3. 稀土氫化物的合成及其在協同反應中的套用。
招收精細化工、套用化學和高分子等專業的博士研究生、碩士研究生以及博士後研究員。熱情歡迎崇尚科學、團結協作、志在創新的有機化學、金屬有機化學、催化化學、材料化學等專業優秀人才加盟本研究室學習深造、開展合作研究。
出版著作和論文
近五年內已發表論文74篇,其中12篇在Angew. Chem. Int. Ed., 6篇在J. Am. Chem. Soc., 2篇在Nature Chem.上發表,1篇在Science上發表,邀請撰寫綜述14篇,申請專利21項。
近年代表性論文
[43] T. Shima, S. Hu, G. Luo, X. Kang, Y. Luo, Z. Hou "Dinitrogen Cleavage and Hydrogenation by a Trinuclear Titanium Polyhydride Complex" Science, 2013, 340, 1549-1552.
[42] F. Guo, M. Nishiura, Y. Li, and Z. Hou "Copolymerization of Isoprene and Nonconjugated α,ω-Dienes by Half-Sandwich Scandium Catalysts with and without a Coordinative Side Arm" Chem. Asian J., 2013, 8, 2471-2482.
[41] Y. Luo, Y. Li, H. Yu, J. Zhao, Y. Chen, Z. Hou, and J. Qu "DFT Studies on the Reduction of Dinitrogen to Ammonia by a Thiolate-Bridged Diiron Complex as a Nitrogenase Mimic" Organometallics, 2012, 31, 335-344.
[40] X. Kang, Y. Song, Y. Luo, G. Li, Z. Hou, and J. Qu "Computional Studies on Isospecific Polymerization of 1-Hexene Catalyzed by cationic Rare Earth Metal Alkyl Complex Bearing a C3 iPr-trisox Ligand" Macromolecules, 2012, 45, 640-651.
[39] J. Cheng, Z. Hou "Cationic terminal hydrido rare earth complexes bearing an amidinate ancillary ligand" Chem. Comm., 2012, 48, 814-816.
[38] L. Pan, K. Zhang, M. Nishiura, and Z. Hou "Chain-Shuttling Polymerization at Two Different Scandium Sites: Regio- and Stereospecific "One-Pot" Block Copolymerization of Styrene, Isoprene, and Butadiene" Angew. Chem. Int. Ed., 2011, 50, 12012-12015.
[37] B. Guan, Z. Hou "Rare-Earth-Catalyzed C-H Bond Addition of pyridine to Olefins"
J. Am. Chem. Soc., 2011, 133, 18086-18089.
[36] J. Oyamada, M. Nishiura, Z. Hou "Scandium-Catalyzed Silylation of Aromatic C-H Bonds" Angew. Chem. Int. Ed., 2011, 50, 10720-10723.
[35] T.Shima, Y. Luo, T. Stewart, R. Bau, G.J.Mclntyre, S.A.Mason, Z. Hou "Molecular heterometallic hydride clusters composed of rare-earth and d-trantion metals" Nature Chem., 2011, 814-820.
[34] F. Guo, M. Nishiura, H. Koshino, and Z. Hou "Scandium-Catalyzed Cyclocopolymerization of 1,5-Hexadiene with Styrene and Ethylene: Efficient Synthesis of Cyclopolyolefins Containing Syndiotactic Styrene-Styrene Sequences and Methylene-1,3-cyclopentane Units" Macromolecules, 2011, 44, 6335-6344.
[33] T. Ohishi, L. Zhang, M. Nishiura, and Z. Hou "Carboxylation of Alkylboranes by N-Heterocyclic Carbene Copper Catalysts:Synthesis of Carboxylic Acids from Terminal Alkenes and Carbon Dioxide" Angew. Chem. Int. Ed., 2011, 50, 8114-8117.
[32] S. Li, J. Cheng, Y. Chen, M. Nishiura, and Z. Hou "Rare Earth Metal Boryl Complexes: Synthesis, Structure, and Insertion of a Carbodiimide and Carbon Monoxide" Angew. Chem. Int. Ed., 2011, 50, 6360-6363.
[31] Yi Luo, Yunjie Luo, J. Qu, Z. Hou "QQ/MM Studies on Scandium-Catalyzed Syndiospecific Copolymerization of Styrene and Ethylene" Organometallics, 2011, 30, 2908-2919.
[30] F. Guo, M. Nishiura, H. Koshino, Z. Hou "Cycloterpolymerization of 1,6-Heptadiene with Ethylene and Styrene Catalyzed by a THF-Free Half-Sandwich Scandium Complex" Macromolecules, 2011, 44, 2400-2403.
[29] M. Nishiura, J. Baldamus, T. Shima, K. mori, Z. Hou "Synthesis and Structures of the C5Me4SiMe3-Supported Polyhydride Complexes over the Full Size Range of the Rare Earth Series" Chem. Eur. J., 2011, 17, 5033-5044.
[28] W. Zhang, Z. Wang, M. Nishiura, Z. Xi, Z. Hou "Ln4(CH2)4 Cubane-Type Rare-Earth Methylidene Complexes Consisting of "(C5Me4SiMe3)LnCH2" Units (Ln=Tm,Lu)" J. Am. Chem. Soc., 2011, 133, 5712-5717.
[27] J. Cheng, T. Shima, Z. Hou "Rare-Earth Polyhydride Complexes Bearing Bis(phosphinophenyl) Amido Princer Ligands" Angew. Chem. Int. Ed., 2011, 50, 1857-1860.
[26] L. Pan, K. Zhang, M. Nishiura, Z. Hou "Syndiospecific Living Copolymerization of Styrene with ε-Caprolactone by Scandium Catalysts" Macromolecules, 2010, 43, 9591-9593.
[25] L. Zhang, J. Cheng , T. Ohishi , Z. Hou "Copper-Catalyzed Direct Carboxylation of C-H Bonds with Carbon Dioxide" Angew. Chem. Int. Ed., 2010, 49, 8670-8673.
[24] X. Li , Z. Hou "Scandium-catalyzed regio- and stereospecific cis-1,4-polymerization of 1,3-cyclohexadiene and copolymerization with ethylene" Macromolecules, 2010, 43, 8904-8909.
[23] M. Nishiura, Z. Hou "Novel polymerization catalysts and hydride clusters from rare-earth metal dialkyls" Nature Chem., 2010, 2, 257-268.
[22] M. Takimoto, S. Usami, Z. Hou "Scandium-Catalyzed Regio- and Stereospecific Methylalumination of Silyloxy/Alkoxy-Substituted Alkynes and Alkenes" J. Am. Chem. Soc., 2009, 131, 18266-18268.
[21] X. Li, M. Nishiura, L. Hu, K. Mori, Z. Hou "Alternating and Random Copolymerization of Isoprene and Ethylene Catalyzed by Cationic Half-Sandwich Scandium Alkyls" J. Am. Chem. Soc., 2009,131,13870-13882.
[20] W-X. Zhang, M. Nishiura, Z. Hou "Synthesis of (Z)-1-Aza-1,3-enynes by the Cross-Coupling of Terminal Alkynes with Isocyanides Catalyzed by Rare-Earth Metal Complexes" Angew. Chem. Int. Ed., 2008, 47, 9700-9703.
[19] L. Zhang, M. Nishiura, M. Yuki, Y. Luo, Z. Hou "Isoprene Polymerization with Yttrium Amidinate Catalysts: Switching the Regio- and Stereoselectivity by Addition of AlMe3" Angew. Chem. Int. Ed., 2008, 47, 2642-2645.
[18] H. Zhang, Y. Luo, Z. Hou "Scandium-Catalyzed Syndiospecific Copolymerization of Styrene with Isoprene" Macromolecules, 2008, 41, 1064-1066.
[17] X. Li , Z. Hou "Organometallic Catalysts for Copolymerization of Cyclic Olefins" Coord. Chem. Rev., 2008, 252, 1842-1869.
[16] X. Li, M. Nishiura, K. Mori, T. Mashiko, Z. Hou "Cationic Scandium Aminobenzyl Complexes. Synthesis, Structure and Unprecedented Catalysis of Copolymerization of 1-Hexene and Dicyclopentadiene" Chem. Commun., 2007, 4137-4139.
[15] Y. Luo, Z. Hou "Computational Study of Ethylene Insertion into the Metal-Hydrogen Bond of the Tetranuclear Yttrium Polyhydrido Complex [(η5-C5Me4SiMe3)YH2]4" Organometallics, 2007, 26, 2941-2944.
[14] L. Zhang, T. Suzuki, Y. Luo, M. Nishiura, Z. Hou "Cationic Alkyl Rare-Earth Metal Complexes Bearing an Ancillary Bis(phosphinophenyl)amido Ligand: A Catalytic System for Living cis-1,4-Polymerization and Copolymerization of Isoprene and Butadiene"
Angew. Chem. Int. Ed., 2007, 46, 1909-1913.
[13] W-X. Zhang, M. Nishiura, Z. Hou "Catalytic Addition of Amine N-H Bonds to Carbodiimides by Half-Sandwich Rare Earth Metal Complexes: Efficient Synthesis of Substituted Guanidines through Amine Protonolysis of Rare-Earth Metal Guanidinates"
Chem. Eur. J. , 2007, 13, 4037-4051.
[12] X. Li, J. Baldamus, M. Nishiura, O. Tardif, Z. Hou "Cationic Rare-Earth Polyhydrido Complexes: Synthesis, Structure, and Catalytic Activity for the cis 1,4-Selective Polymerization of 1,3-Cyclohexadiene" Angew. Chem. Int. Ed., 2006, 45, 8184-8188.
[11] T. Shima, Z. Hou "Hydrogenation of Carbon Monoxide by Tetranuclear Rare Earth Metal Polyhydrido Complexes. Selective Formation of Ethylene and Isolation of Well-Defined Polyoxo Rare Earth Metal Clusters" J. Am. Chem. Soc., 2006, 128, 8124-8125.
[10] Y. Liu, M. Nishiura, Y. Wang, Z. Hou "π-Conjugated Aromatic Enynes as a Single-Emitting Component for White Electroluminescence" J. Am. Chem. Soc., 2006, 128, 5592-5593.
[9] Z. Hou, Y. Luo, X. Li "Cationic Rare Earth Metal Alkyls as Novel Catalysts for Olefin Polymerization and Copolymerization" J. Organomet. Chem., 2006, 691, 3114-3121.
[8] M. Takimoto, Z. Hou "Hydrogen at the Flick of a Switch" Nature, 2006, 443, 400-401.
[7] W.-X. Zhang, M. Nishiura, Z. Hou "Catalytic Addition of Terminal Alkynes to Carbodiimides by Half-Sandwich Rare Earth Metal Complexes" J. Am. Chem. Soc., 2005, 127, 16788-16789.
[6] L. Zhang, Y. Luo, Z. Hou "Unprecedented Isospecific 3,4-Polymerization of Isoprene by Cationic Rare Earth Metal Alkyl Species Resulting from a Binuclear Precursor" J. Am. Chem. Soc., 2005, 127, 14562-14563.
[5] X. Li, J. Baldamus, Z. Hou "Alternating Ethylene-Norbornene Copolymerization Catalyzed by Cationic Half-Sandwich Scandium Complexes" Angew. Chem. Int. Ed., 2005, 44, 962-964.
[4] D. Cui, M. Nishiura, Z. Hou "Rare Earth Metal Imido Complexes and their Reactions with Benzonitrile" Angew. Chem. Int. Ed., 2005, 44, 959-961.
[3] Y. Luo, J. Baldamus, Z. Hou "Scandium Half-Metallocene-Catalyzed Syndiospecific Styrene Polymerization and Styrene-Ethylene Copolymerization: Unprecedented Incorporation of Syndiotactic Styrene-Styrene Sequences in Styrene-Ethylene Copolymers" J. Am. Chem. Soc., 2004, 126, 13910-13911.
[2] O. Tardif, D. Hashizume, Z. Hou "Hydrogenation of Carbon Dioxide and Aryl Isocyanates by a Tetranuclear Tetrahydrido Yttrium Complex. Isolation, Structures, and CO2-Insertion Reactions of Methylene Diolate and 3-Oxo Yttrium Complexes"
J. Am. Chem. Soc., 2004, 126, 8080-8081.
[1] D. Cui, O. Tardif, Z. Hou "Tetranuclear Rare Earth Metal Polyhydrido Complexes Composed of "(C5Me4SiMe3)LnH2" Units. Unique Reactivities toward Unsaturated C-C, C-N, and C-O Bonds" J. Am. Chem. Soc., 2004, 126, 1312-1313.
工作成果(獎勵、專利等)
1996年 日本配位化學會青年科學家獎
1997年 日本稀土學會青年科學家獎
2000年 日本有機合成化學進步獎
2007年 日本學術振興會獎
2007年 日本化學會學術獎
2007年 三井化學催化科學獎
2008年 教育部長江學者
2008年 日本文部科學大臣表彰:科學技術獎
2009年 日本稀土學會獎
2011年 國家高層次“千人計畫”學者
2012年 日本高分子學會獎
在讀學生人數10人
畢業學生人數12人