何成[大連理工大學化工學院副教授]

何成,大連理工大學化工學院副教授。從事超分子功能配位化學方向的科研工作,利用拓撲可控的金屬-有機大環和籠狀結構,模擬生命體系的酶化學過程,實現對生物小分子的高選擇性成像檢測和精細化工反應的高立體選擇性催化,並開展利用光等清潔能源驅動的化學反應研究。

個人簡介

1991年畢業於北京大學技術物理系套用化學專業,獲學士學位

1994年畢業於北京大學技術物理系套用化學專業,獲碩士學位

2000年畢業於南京大學配位化學研究所,獲博士學位

2000-2002,北京大學稀土中心博士後

2002-2003,韓國浦項理工大學化學系博士後

2003-2005,德國哥廷根大學無機化學研究所洪堡博士後

2006-, 大連理工大學化工學院,副教授

研究領域

(研究課題)

國家自然科學基金項目:

1.金屬有機籠狀結構的合成與生物小分子識別;

2.面向立體選擇性碳碳偶聯反應的光化學分子反應器的研究

3.基於金屬有機框架結構的光催化制氫研究

碩博研究方向

金屬有機限域空間內的超分子化學研究

單一手性分子材料的構築與套用

代表性論文:

1. P. Y. Wu, C. He*, J. Wang, X. J. Peng, X. Z. Li, Y. L. An, and C. Y. Duan*,"Photoactive Chiral Metal?Organic Frameworks for Light-Driven Asymmetric α?Alkylation of Aldehydes" J. Am. Chem. Soc. 2012, 134, 14991.

2. X. Jing, C. He, D. P. Dong, L. L. Yang and C. Y. Duan*, "Homochiral Crystallization of Metal–Organic Silver Frameworks:Asymmetric [3+2] Cycloaddition of an Azomethine Ylide" Angew. Chem. Int. Ed. 2012, 51, 10127

3. J. Wang, C. He*, P. Y. Wu, J. Wang, C. Y. Duan*, "An Amide-Containing Metal-Organic Tetrahedron Responding to a Spin-Trapping Reaction in a Fluorescent Enhancement Manner for Biological Imaging of NO in Living Cells" J. Am. Chem. Soc. 2011, 133, 12402.

4. C. He, Z. H. Lin, Z. He, C. Y. Duan*, C. H. Xu, Z. M. Wang, C. H. Yan*, “Metal-tunable nanocages as artificial chemosensors”, Angew. Chem. Int. Ed. 2008, 47, 877-881.

5. C. He, X. Wu, J. C. Kong, T. liu, Xi. L. Zhang and C. Y. Duan*, "A hexanuclear gadolinium–organic octahedron as a sensitive MRI contrast agent for selectively imaging glucosamine in aqueous media" Chem. Commun. 2012, 48, 9290.

6. Y. Jiao, J. Zhang, L. J. Zhang, Z. H. Lin, C. He*, C. Y. Duan, "Metal–organic polyhedra containing 36 and 24 folds of amide groups for selective luminescent recognition of natural disaccharides" Chem. Commun 2012, 48, 6022.

7. L. Zhao, S. Y. Qu, C. He*, R. Zhang, C. Y. Duan, "Face-driven octanuclear cerium(IV) luminescence polyhedra: synthesis and luminescent sensing natural saccharides" Chem. Commun. 2011, 47, 9387.

8. X. Wu, C. He, X. Wu, S. Y. Qu, Chunying Duan*, "An L-proline functionalized metallo-organic triangle as size-selective homogeneous catalyst for asymmetry catalyzing aldol reactions." Chem. Commun. 2011, 47, 8415.

9 Y. Liu, X. Wu, C. He,* Y. Jiao, C. Y. Duan, “Self-assembly of cerium-based metal-organic tetrahedrons for size-selectively luminescent sensing natural saccharides”, Chem. Commun. 2009, 48 , 7554.

10 Y. Liu, R. Zhang, C. He*, D. B. Dang, C. Y. Duan*, “A palladium(II) triangle as building blocks of microporous molecular materials: structures and catalytic performance”Source: Chem. Commun. 2010, 46, 746-748.

11. H. M. Wu, C. He*, Z. H. Lin, Y. Liu, C. Y. Duan*, “Metallohelical Triangles for Selective Detection of Adenosine Triphosphate in Aqueous Media” Inorg. Chem. 2009, 48, 408-410.

12, W. Huang, C. X. Song, C. He*, G. J. Lv, X. Y. Hu, X. Zhu, C. Y. Duan*. "Recognition Preference of Rhodamine-Thiospirolactams for Mercury(II) in Aqueous Solution" Inorg. Chem. 2009, 48, 5061.

13. G. J. He, Y. G. Zhao, C. He*, Y. Liu, C. Y. Duan*, "Turn-On" fluorescent sensor for Hg2+ via displacement approach” Inorg. Chem. 2008, 47, 5169-5176

14. J. Wang, H. M. Wu, C. He*, L. Zhao, C. Y. Duan, "Metal-Organic Cyclohelicates as Optical Receptors for Glutathione: Syntheses Structures and Host-Guest Behaviors" Chem. Asian J. 2011, 6, 1225.
15. Y.Liu, Z. H. Lin, C. He*, L. Zhao, C. Y. Duan, “A symmetry-controlled and face-driven approach for the assembly of cerium-based molecular polyhedra” Dalton Trans. 2010, 39, 11122
16.X. Zhu, C. He*, D. Dong, Y. Liu and C. Y. Duan*, “Cerium-based triple-stranded helicates as luminescent chemosensors for the selective sensing of magnesium ions” Dalton Trans. 2010, 39, 11051
17. Y. Liu, X. Wu, C. He*, Z. Y. Li, C. Y. Duan*, “ Metal-organic polyhedra for selective sensing of ribonucleosides through the cooperation of hydrogen-bonding interactions” Dalton Trans. 2010, 39, 7727.
18. W. Huang, X. Zhu, D. Y. Wu, C. He*, X. Y. Hu, C. Y. Duan*. "Structural modification of rhodamine-based sensors toward highly selective mercury detection in mixed organic/aqueous media. Dalton Transactions" 2009, 10457.
19. W. Huang, D. Y. Wu, D. Guo*, X. Zhu, C. He*, Q. J. Meng, C. Y. Duan*, "Efficient near-infrared emission of a Ytterbium(III) compound with a green light rhodamine donor" Dalton Transactions. 2009, 2081.
20. Y. Liu, X. Wu, C. He*, R. Zhang, C. Y. Duan*, "A truncated octahedral nanocage for fluorescent detection of nucleoside" Dalton Transactions. 2008, 5866.
21. Q. Z. Sun, M. L. Wei, Y. Bai, C. He*, Q. J. Meng, C. Y. Duan*. "Entanglement of individual coordination polymers having helicates as building intermediates" Dalton Transactions. 2007, 36, 4089
22. X. Wu, Z. H. Lin, C. He* and C. Y. Duan, “Catalytic performance of lanthanide molecular solids containing well-modified metal–organic octahedral” New J. Chem. 2012, 36, 161.
23. H. Zhang, L. X. Xie, W. B. Yan, C. He*, X. Cao, C. Y. Duan*, "Conformational switching fluorescent chemodosimeter for the selective detection of silver(I) ions" New J. Chem. 2009, 33, 1478.
24. C. He, B. G. Zhang, L. X. Xie, Y. Liu, C. Y. Duan* "Stereoselective association of ferrocene-contained molecular clips in coordination polymers" CrystEngComm. 2008, 10, 759.
25. C. He, Y. G. Zhao, D. Guo*, Z. H. Lin, C. Y. Duan* "Chirality transfer through helical motifs in coordination compounds" Euro. J. Inorg. Chem. 2007, 22, 3451.

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